TRIPHENYLBORANE
Synonym(s):Triphenylborane
- CAS NO.:960-71-4
- Empirical Formula: C18H15B
- Molecular Weight: 242.12
- MDL number: MFCD00003007
- EINECS: 213-504-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is TRIPHENYLBORANE?
The Uses of TRIPHENYLBORANE
TRIPHENYLBORANE is a type of Lewis acid used as catalyst and intermediate.
The Uses of TRIPHENYLBORANE
Triphenylborane is used as a precursor in the production of pyridine-triphenylborane complex, which is used as a catalyst for the polymerization of acrylic esters. It is also used in the hydrocyanation of butadiene to adiponitrile. It is involved in the synthesis of 3-phenyl-cyclohexene by reacting with acetic acid cyclohex-2-enyl ester in presence of palladium bis(dibenzylideneacetone) and triphenylphosphine as a catalyst.
Synthesis Reference(s)
The Journal of Organic Chemistry, 52, p. 5564, 1987 DOI: 10.1021/jo00234a011
Hazard
TRIPHENYLBORANE is a severe eye irritant.
Purification Methods
Recrystallise the borane three times from Et2O or *C6H6 under N2 and dry it at 130o. It can be distilled in a high vacuum at 300-350o and has been distilled (b 195-215o/~15mm) in vacuum using a bath temperature of 240-330o. N2 is introduced into the apparatus before dismantling. It forms complexes with amines. [Nielsen et al. Chem Ind (London) 1069 1957, Wittig et al. Justus Liebigs Ann Chem 563 110 1949, Bent & Dorfman J Am Chem Soc 57 1259 1935, Beilstein 16 IV 1623.]
Properties of TRIPHENYLBORANE
Melting point: | 145 °C (lit.) |
Boiling point: | 203 °C/15 mmHg (lit.) |
Density | 0.898 g/mL at 25 °C |
Flash point: | 1 °F |
form | Powder |
color | off-white |
Water Solubility | Soluble in aromatic solvents. Insoluble in water. |
Sensitive | Air Sensitive |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
BRN | 1961313 |
CAS DataBase Reference | 960-71-4(CAS DataBase Reference) |
EPA Substance Registry System | Borane, triphenyl- (960-71-4) |
Safety information for TRIPHENYLBORANE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 |
GHS Hazard Statements |
H228:Flammable solids |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. |
Computed Descriptors for TRIPHENYLBORANE
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
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