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HomeProduct name listTRIPHENYLBORANE

TRIPHENYLBORANE

Synonym(s):Triphenylborane

  • CAS NO.:960-71-4
  • Empirical Formula: C18H15B
  • Molecular Weight: 242.12
  • MDL number: MFCD00003007
  • EINECS: 213-504-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
TRIPHENYLBORANE Structural

What is TRIPHENYLBORANE?

The Uses of TRIPHENYLBORANE

TRIPHENYLBORANE is a type of Lewis acid used as catalyst and intermediate.

The Uses of TRIPHENYLBORANE

Triphenylborane is used as a precursor in the production of pyridine-triphenylborane complex, which is used as a catalyst for the polymerization of acrylic esters. It is also used in the hydrocyanation of butadiene to adiponitrile. It is involved in the synthesis of 3-phenyl-cyclohexene by reacting with acetic acid cyclohex-2-enyl ester in presence of palladium bis(dibenzylideneacetone) and triphenylphosphine as a catalyst.

Synthesis Reference(s)

The Journal of Organic Chemistry, 52, p. 5564, 1987 DOI: 10.1021/jo00234a011

Hazard

TRIPHENYLBORANE is a severe eye irritant.

Purification Methods

Recrystallise the borane three times from Et2O or *C6H6 under N2 and dry it at 130o. It can be distilled in a high vacuum at 300-350o and has been distilled (b 195-215o/~15mm) in vacuum using a bath temperature of 240-330o. N2 is introduced into the apparatus before dismantling. It forms complexes with amines. [Nielsen et al. Chem Ind (London) 1069 1957, Wittig et al. Justus Liebigs Ann Chem 563 110 1949, Bent & Dorfman J Am Chem Soc 57 1259 1935, Beilstein 16 IV 1623.]

Properties of TRIPHENYLBORANE

Melting point: 145 °C (lit.)
Boiling point: 203 °C/15 mmHg (lit.)
Density  0.898 g/mL at 25 °C
Flash point: 1 °F
form  Powder
color  off-white
Water Solubility  Soluble in aromatic solvents. Insoluble in water.
Sensitive  Air Sensitive
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN  1961313
CAS DataBase Reference 960-71-4(CAS DataBase Reference)
EPA Substance Registry System Borane, triphenyl- (960-71-4)

Safety information for TRIPHENYLBORANE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
GHS Hazard Statements H228:Flammable solids
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

Computed Descriptors for TRIPHENYLBORANE

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