TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
- CAS NO.：13170-43-9
- Empirical Formula: C4H11ClMgSi
- Molecular Weight: 146.97
- MDL number: MFCD00009916
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-30 18:52:02
What is TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE?
Chemical properties
Grey liquid
The Uses of TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc.
The Uses of TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides.
What are the applications of Application
(Trimethylsilyl)methylmagnesium chloride solution is a reagent used in a variety of nickel catalyzed reactions
Preparation
From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent.
Properties of TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
| Melting point: | 105.8-106.4 °C |
| Density | 1.04 |
| Flash point: | -40°C |
| storage temp. | Flammables + water-Freezer (-20°C)e area |
| solubility | Sol ethereal solvents; reacts with protic solvents. |
| form | Low Melting Solid |
| color | Clear colorless to yellow to greenish |
| Specific Gravity | 0.912 |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3587255 |
| CAS DataBase Reference | 13170-43-9(CAS DataBase Reference) |
Safety information for TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H313:Acute toxicity,dermal H314:Skin corrosion/irritation H318:Serious eye damage/eye irritation H336:Specific target organ toxicity,single exposure; Narcotic effects |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P310:Immediately call a POISON CENTER or doctor/physician. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE
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product: 13170-43-9 (Trimethylsilyl)methylmagnesium 99%
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product: 13170-43-9 TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE (1.0M IN ETHER)
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