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HomeProduct name listTrimethyloxonium Tetrafluoroborate

Trimethyloxonium Tetrafluoroborate

  • CAS NO.:420-37-1
  • Empirical Formula: C3H9BF4O
  • Molecular Weight: 147.91
  • MDL number: MFCD00011798
  • EINECS: 206-994-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-01 09:07:02
Trimethyloxonium Tetrafluoroborate Structural

What is Trimethyloxonium Tetrafluoroborate?

Chemical properties

This substance is a white to off-white crystals that is prone to water sensitivity and displays a level of hygroscopicity.

The Uses of Trimethyloxonium Tetrafluoroborate

Trimethyloxonium Tetrafluoroborate is a trialkylated oxonium used as a methylation agent in organic synthesis.

The Uses of Trimethyloxonium Tetrafluoroborate

Trimethyloxonium tetrafluoroborate act as a avmethylating agent and activates C-X multiple bonds. It is involved in the esterification of polyfunctional carboxylic acids. It acts as a catalyst in the polymerization of cyclic sulfides and ethers. Further, it is used in Beckmann rearrangement of oximes.

The Uses of Trimethyloxonium Tetrafluoroborate

Reagent for the methylation of hydroxyl groups recently used in a complex, multistep synthesis directed towards spirastrellolide, a marine natural product.

Health Hazard

Trimethyloxonium Tetrafluoroborate is a potent alkylating agent, with its non-volatile nature reducing associated hazards. Nevertheless, it produces strong acids upon contact with water, so it is important to exercise caution and prevent water contact during its application.

Properties of Trimethyloxonium Tetrafluoroborate

Melting point: 200 °C
storage temp.  Store at +2°C to +8°C.
solubility  Soluble in nitrobenzene, nitromethane, chloroform, hot acetone, liquid sulfur dioxide. Slightly soluble in dichloromethane. Insoluble in common organic solvents.
form  Crystals
color  White to off-white
Sensitive  Moisture Sensitive
BRN  3597303
InChI InChI=1S/C3H9O.BF4/c1-4(2)3;2-1(3,4)5/h1-3H3;/q+1;-1
CAS DataBase Reference 420-37-1(CAS DataBase Reference)
EPA Substance Registry System Oxonium, trimethyl-, tetrafluoroborate(1-) (420-37-1)

Safety information for Trimethyloxonium Tetrafluoroborate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Trimethyloxonium Tetrafluoroborate

InChIKey JDFKFXJJAIJXPP-UHFFFAOYSA-M
SMILES [B-](F)(F)(F)F.[O+](C)(C)C

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