Trimethyloxonium Tetrafluoroborate
- CAS NO.:420-37-1
- Empirical Formula: C3H9BF4O
- Molecular Weight: 147.91
- MDL number: MFCD00011798
- EINECS: 206-994-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-01 09:07:02
What is Trimethyloxonium Tetrafluoroborate?
Chemical properties
This substance is a white to off-white crystals that is prone to water sensitivity and displays a level of hygroscopicity.
The Uses of Trimethyloxonium Tetrafluoroborate
Trimethyloxonium Tetrafluoroborate is a trialkylated oxonium used as a methylation agent in organic synthesis.
The Uses of Trimethyloxonium Tetrafluoroborate
Trimethyloxonium tetrafluoroborate act as a avmethylating agent and activates C-X multiple bonds. It is involved in the esterification of polyfunctional carboxylic acids. It acts as a catalyst in the polymerization of cyclic sulfides and ethers. Further, it is used in Beckmann rearrangement of oximes.
The Uses of Trimethyloxonium Tetrafluoroborate
Reagent for the methylation of hydroxyl groups recently used in a complex, multistep synthesis directed towards spirastrellolide, a marine natural product.
Health Hazard
Trimethyloxonium Tetrafluoroborate is a potent alkylating agent, with its non-volatile nature reducing associated hazards. Nevertheless, it produces strong acids upon contact with water, so it is important to exercise caution and prevent water contact during its application.
Properties of Trimethyloxonium Tetrafluoroborate
Melting point: | 200 °C |
storage temp. | Store at +2°C to +8°C. |
solubility | Soluble in nitrobenzene, nitromethane, chloroform, hot acetone, liquid sulfur dioxide. Slightly soluble in dichloromethane. Insoluble in common organic solvents. |
form | Crystals |
color | White to off-white |
Sensitive | Moisture Sensitive |
BRN | 3597303 |
InChI | InChI=1S/C3H9O.BF4/c1-4(2)3;2-1(3,4)5/h1-3H3;/q+1;-1 |
CAS DataBase Reference | 420-37-1(CAS DataBase Reference) |
EPA Substance Registry System | Oxonium, trimethyl-, tetrafluoroborate(1-) (420-37-1) |
Safety information for Trimethyloxonium Tetrafluoroborate
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H314:Skin corrosion/irritation |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Trimethyloxonium Tetrafluoroborate
InChIKey | JDFKFXJJAIJXPP-UHFFFAOYSA-M |
SMILES | [B-](F)(F)(F)F.[O+](C)(C)C |
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