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HomeProduct name listTRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE

TRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE

Synonym(s):β,β′-Bistyryl;DPB

  • CAS NO.:538-81-8
  • Empirical Formula: C16H14
  • Molecular Weight: 206.28
  • MDL number: MFCD00004791
  • EINECS: 629-554-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-09-26 16:29:58
TRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE Structural

What is TRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE?

Chemical properties

light yellow crystalline powder

The Uses of TRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE

trans,trans-1,4-Diphenyl-1,3-butadiene reacts with Rieke metal complexes of barium and strontium to prepare metal-diene reagents, which is used for the carbocyclization with dichloroalkanes.

Definition

ChEBI: 1,4-diphenylbutadiene is an alkadiene. It has a role as a fluorochrome.

Purification Methods

Its solution in pet ether (b 60-70o) is chromatographed on an alumina-Celite column (4:1), and the column is washed with the same solvent. The main zone is cut out, eluted with ethanol and transferred to pet ether, which is then dried and evaporated [Pinckard et al. J Am Chem Soc 70 1938 1948]. Recrystallise it from hexane. [Beilstein 5 H 676, 9 IV 2319.]

Properties of TRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE

Melting point: 150-152 °C(lit.)
Boiling point: 350 °C(lit.)
Density  1.151 g/cm3
refractive index  1.5000 (estimate)
Flash point: 350°C/720mm
storage temp.  Sealed in dry,Room Temperature
form  Crystals or Crystalline Powder
color  White to slightly yellow
Water Solubility  Slightly soluble in water.
Merck  14,3320
BRN  1905937
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 538-81-8(CAS DataBase Reference)

Safety information for TRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for TRANS,TRANS-1,4-DIPHENYL-1,3-BUTADIENE

InChIKey JFLKFZNIIQFQBS-FNCQTZNRSA-N

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