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HomeProduct name listTetraphenylsilane

Tetraphenylsilane

  • CAS NO.:1048-08-4
  • Empirical Formula: C24H20Si
  • Molecular Weight: 336.5
  • MDL number: MFCD00014069
  • EINECS: 213-881-3
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-07 20:48:41
Tetraphenylsilane Structural

What is Tetraphenylsilane?

Chemical properties

White solid. Very stable and inert. Combustible.

The Uses of Tetraphenylsilane

Heat-transfer medium, polymers.

Preparation

Tetraphenylsilane (TPSi) can be obtained by reaction of phenylmagnesium bromide with tetrachlorosilane or by reaction of phenyllithium with alkoxysilanes.TETRAPHENYLSILANE

Purification Methods

It crystallises from *benzene as clear colorless bladed needles. It decomposes at ~360o/~760mm on attempted distillation. [George et al. J Am Chem Soc 77 6647 1955, Polis Chem Ber 98 1540 1885, Drew & Landuist J Chem Soc 1480 1935,s Beilstein 16 H 901, 16 I 525, 16 II 606, 16 III 1199, 16 IV 1372.]

References

[1] Furgal J, et al. Nucleophilic Attack of R-lithium at Tetrahedral Silicon in Alkoxysilanes. An Alternate Mechanism. Bulletin of the Chemical Society of Japan, 2016.

Properties of Tetraphenylsilane

Melting point: 236 °C
Boiling point: 228 °C
Density  1.078
Flash point: 193°C
form  solid
color  White to Almost white
Specific Gravity 1.078
Water Solubility  Insoluble in water.
Hydrolytic Sensitivity 1: no significant reaction with aqueous systems
BRN  1885911
CAS DataBase Reference 1048-08-4(CAS DataBase Reference)
EPA Substance Registry System Silane, tetraphenyl- (1048-08-4)

Safety information for Tetraphenylsilane

Computed Descriptors for Tetraphenylsilane

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