Tetramethylene sulfoxide
Synonym(s):Tetramethylene sulfoxide
- CAS NO.:1600-44-8
- Empirical Formula: C4H8OS
- Molecular Weight: 104.17
- MDL number: MFCD00005477
- EINECS: 216-493-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-11-28 16:31:44
What is Tetramethylene sulfoxide?
Chemical properties
clear colorless to yellow liquid
The Uses of Tetramethylene sulfoxide
In a comparative study of aromatic fluorodenitration with Potassium fluoride, in several dipolar aprotic solvents, a much faster reaction rate was observed with DMSO or tetramethylene sulfoxide than with the more commonly used Sulfolane.
Definition
ChEBI: Tetrahydrothiophene 1-oxide is a member of tetrahydrothiophenes.
Synthesis Reference(s)
Journal of the American Chemical Society, 63, p. 2939, 1941 DOI: 10.1021/ja01856a021
The Journal of Organic Chemistry, 50, p. 1787, 1985 DOI: 10.1021/jo00210a055
Synthetic Communications, 24, p. 2393, 1994 DOI: 10.1080/00397919408010545
Purification Methods
Shake the oxide with BaO for 4 days, then distil it from CaH2 under reduced pressure. [Beilstein 17 III/IV 36, 17/1 V 38.]
Properties of Tetramethylene sulfoxide
Boiling point: | 235-237 °C(lit.) |
Density | 1.158 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | >230 °F |
form | Liquid |
color | Clear colorless to yellow |
Water Solubility | Fully miscible in water. |
BRN | 105274 |
Dielectric constant | 5.6(25℃) |
CAS DataBase Reference | 1600-44-8(CAS DataBase Reference) |
EPA Substance Registry System | Thiophene, tetrahydro-, 1-oxide (1600-44-8) |
Safety information for Tetramethylene sulfoxide
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for Tetramethylene sulfoxide
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
Tetramethylguanidine
Tetramethylpyrazine
Tetramethylbenzidine
TETRAHYDRO-THIOPHEN-3-OL
4-BUTYROTHIOLACTONE
3-ETHOXYSULFOLANE
(1,1-DIOXIDOTETRAHYDROTHIEN-3-YL)ACETIC ACID
3,4-DICHLOROSULFOLANE
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