TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
- CAS NO.:109704-53-2
- Empirical Formula: C10H22BNO6
- Molecular Weight: 263.1
- MDL number: MFCD00012196
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:37
What is TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE?
The Uses of TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
Selective reducing agent.
Purification Methods
If impure, wash it with freshly distilled Et2O and dry it overnight in a vacuum to give a free flowing powder. Check 1H NMR, and if still suspect prepare it freshly from Me4NBH4 and AcOH in *C6H6 and store it away from moisture [Banus et al. J Am Chem Soc 74 2346 1952, Evans & Chipman Tetrahedron Lett 27 5939 1986]. Itisan IRRITANT and MOISTURE SENSITIVE.
Properties of TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
Melting point: | 93-98 °C(lit.) |
storage temp. | 2-8°C |
solubility | slightly sol. in dichloromethane |
form | powder to crystal |
color | White to Almost white |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
BRN | 8238791 |
Safety information for TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P231+P232:Handle under inert gas. Protect from moisture. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
InChIKey | LCFZZOGKVOTFPU-UHFFFAOYSA-N |
New Products
4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
Tetramethylammonium acetate
Sodium triacetoxyborohydride
Chlorotriethylsilane
TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE
FLUOROTRIETHYLSILANE
Triethylsilane
Triisopropylsilyl chloride
N,N,N',N'-TETRAMETHYLDIAMINOMETHANE
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