TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
- CAS NO.:109704-53-2
- Empirical Formula: C10H22BNO6
- Molecular Weight: 263.1
- MDL number: MFCD00012196
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:37
What is TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE?
The Uses of TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
Selective reducing agent.
Purification Methods
If impure, wash it with freshly distilled Et2O and dry it overnight in a vacuum to give a free flowing powder. Check 1H NMR, and if still suspect prepare it freshly from Me4NBH4 and AcOH in *C6H6 and store it away from moisture [Banus et al. J Am Chem Soc 74 2346 1952, Evans & Chipman Tetrahedron Lett 27 5939 1986]. Itisan IRRITANT and MOISTURE SENSITIVE.
Properties of TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
Melting point: | 93-98 °C(lit.) |
storage temp. | 2-8°C |
solubility | slightly sol. in dichloromethane |
form | powder to crystal |
color | White to Almost white |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
BRN | 8238791 |
Safety information for TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P231+P232:Handle under inert gas. Protect from moisture. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
InChIKey | LCFZZOGKVOTFPU-UHFFFAOYSA-N |
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5,6-Dimethoxyindanone 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
Tetramethylammonium acetate
Sodium triacetoxyborohydride
Chlorotriethylsilane
TRIISOPROPYLSILYL TRIFLUOROMETHANESULFONATE
FLUOROTRIETHYLSILANE
Triethylsilane
Triisopropylsilyl chloride
N,N,N',N'-TETRAMETHYLDIAMINOMETHANE
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