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HomeProduct name listTetrabutylphosphonium bromide

Tetrabutylphosphonium bromide

  • CAS NO.:3115-68-2
  • Empirical Formula: C16H36BrP
  • Molecular Weight: 339.33
  • MDL number: MFCD00011853
  • EINECS: 221-487-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-12 09:16:57
Tetrabutylphosphonium bromide Structural

What is Tetrabutylphosphonium bromide?

Chemical properties

Tetrabutylphosphonium bromide is WHITE TO CREAM CRYSTALLINE POWDER

The Uses of Tetrabutylphosphonium bromide

Tetrabutylphosphonium bromide (TBPB) is a quaternary salt which can be used:
As a medium to disperse ruthenium catalyst for the synthesis of ethylene glycol from synthesis gas via ruthenium melt catalysis.
As a catalyst supported on silica or alumina for the halogen exchange reaction to synthesize alkyl bromide from alkyl chloride.
To synthesize various ionic liquids on mixing with different proportions of 1,3-dimethylurea for capturing NO gas.
As a hydrogen-bond acceptor along with levulinic acid as a hydrogen-bond donor for the preparation of deep eutectic solvents to separate toluene from toluene/n-hexane mixtures.
To prepare ionic semiclathrate hydrates.

The Uses of Tetrabutylphosphonium bromide

Tetrabutylphosphonium bromide is a useful synthetic reagent used in proteomics research.

The Uses of Tetrabutylphosphonium bromide

Tetra-n-butylphosphonium bromide is used as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination e.g. as catalyst for the dealkoxycarbonylation of malonates and -keto esters by heating in stearic acid. used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles. It is a synthetic reagent used in proteomics research.

What are the applications of Application

Tetrabutylphosphonium bromide is a useful synthetic reagent used in proteomics research.

Flammability and Explosibility

Non flammable

Properties of Tetrabutylphosphonium bromide

Melting point: 100-103 °C(lit.)
Density  1.8[at 20℃]
vapor pressure  0.018Pa at 25℃
Flash point: 290 °C
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  crystal
color  white
Water Solubility  ca 70 g/100 mL
Sensitive  Hygroscopic
BRN  4160474
Stability: hygroscopic
CAS DataBase Reference 3115-68-2(CAS DataBase Reference)
NIST Chemistry Reference Phosphonium bromide, tetrabutyl(3115-68-2)
EPA Substance Registry System Phosphonium, tetrabutyl-, bromide (3115-68-2)

Safety information for Tetrabutylphosphonium bromide

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H290:Corrosive to Metals
H302:Acute toxicity,oral
H311:Acute toxicity,dermal
H317:Sensitisation, Skin
H318:Serious eye damage/eye irritation
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for Tetrabutylphosphonium bromide

InChIKey JRMUNVKIHCOMHV-UHFFFAOYSA-M

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