Tetrabutylphosphonium bromide
- CAS NO.:3115-68-2
- Empirical Formula: C16H36BrP
- Molecular Weight: 339.33
- MDL number: MFCD00011853
- EINECS: 221-487-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-12 09:16:57
What is Tetrabutylphosphonium bromide?
Chemical properties
Tetrabutylphosphonium bromide is WHITE TO CREAM CRYSTALLINE POWDER
The Uses of Tetrabutylphosphonium bromide
Tetrabutylphosphonium bromide (TBPB) is a quaternary salt which can be used:
As a medium to disperse ruthenium catalyst for the synthesis of ethylene glycol from synthesis gas via ruthenium melt catalysis.
As a catalyst supported on silica or alumina for the halogen exchange reaction to synthesize alkyl bromide from alkyl chloride.
To synthesize various ionic liquids on mixing with different proportions of 1,3-dimethylurea for capturing NO gas.
As a hydrogen-bond acceptor along with levulinic acid as a hydrogen-bond donor for the preparation of deep eutectic solvents to separate toluene from toluene/n-hexane mixtures.
To prepare ionic semiclathrate hydrates.
The Uses of Tetrabutylphosphonium bromide
Tetrabutylphosphonium bromide is a useful synthetic reagent used in proteomics research.
The Uses of Tetrabutylphosphonium bromide
Tetra-n-butylphosphonium bromide is used as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination e.g. as catalyst for the dealkoxycarbonylation of malonates and -keto esters by heating in stearic acid. used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles. It is a synthetic reagent used in proteomics research.
What are the applications of Application
Tetrabutylphosphonium bromide is a useful synthetic reagent used in proteomics research.
Flammability and Explosibility
Non flammable
Properties of Tetrabutylphosphonium bromide
Melting point: | 100-103 °C(lit.) |
Density | 1.8[at 20℃] |
vapor pressure | 0.018Pa at 25℃ |
Flash point: | 290 °C |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | crystal |
color | white |
Water Solubility | ca 70 g/100 mL |
Sensitive | Hygroscopic |
BRN | 4160474 |
Stability: | hygroscopic |
CAS DataBase Reference | 3115-68-2(CAS DataBase Reference) |
NIST Chemistry Reference | Phosphonium bromide, tetrabutyl(3115-68-2) |
EPA Substance Registry System | Phosphonium, tetrabutyl-, bromide (3115-68-2) |
Safety information for Tetrabutylphosphonium bromide
Signal word | Danger |
Pictogram(s) |
Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 Environment GHS09 |
GHS Hazard Statements |
H290:Corrosive to Metals H302:Acute toxicity,oral H311:Acute toxicity,dermal H317:Sensitisation, Skin H318:Serious eye damage/eye irritation H411:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for Tetrabutylphosphonium bromide
InChIKey | JRMUNVKIHCOMHV-UHFFFAOYSA-M |
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