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HomeProduct name listtert-Butyl Hypochlorite

tert-Butyl Hypochlorite

  • CAS NO.:507-40-4
  • Empirical Formula: C4H9ClO
  • Molecular Weight: 108.57
  • MDL number: MFCD00037105
  • EINECS: 208-072-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-11 14:08:43
tert-Butyl Hypochlorite Structural

What is tert-Butyl Hypochlorite?

Chemical properties

yellowish liquid with an irritating odour

The Uses of tert-Butyl Hypochlorite

Dehydration of alcohols; N- and C-chlorinations.

The Uses of tert-Butyl Hypochlorite

Hypochlorous Acid tert-Butyl Ester_x000D__x000D_DISCONTINUED (cas# 507-40-4) is a compound useful in organic synthesis.

General Description

A slightly yellowish liquid with a pungent odor. Water insoluble. Flash point near 0°F. Corrosive to the skin, eyes, and mucous membranes.

Air & Water Reactions

May ignite on contact with air or moist air. May burn rapidly with flare-burning effect. Water insoluble. Decomposed exothermically by water with the evolution of toxic chlorine gas.

Reactivity Profile

HYPOCHLOROUS ACID TERT-BUTYL ESTER decomposes exothermically when exposed to UV light to give acetone and chloromethane. Glass containers have burst because of pressure buildup after exposure to fluorescent lighting or daylight. Reacts violently with rubber. Should not be heated to its boiling point.

Health Hazard

Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.

Fire Hazard

Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.

Properties of tert-Butyl Hypochlorite

Boiling point: 79.6℃ (750 Torr)
Density  0.96
refractive index  1.4010-1.4050
storage temp.  Refrigerator
solubility  Chloroform (Sparingly), Ethyl Acetate (Slightly)
form  Oil
color  Pale Yellow to Yellow
Merck  14,1571
Stability: Unstable. Light-sensitive. Highly flammable. Incompatible with strong oxidizing agents. Keep refrigerated below 10 C.
EPA Substance Registry System Hypochlorous acid, 1,1-dimethylethyl ester (507-40-4)

Safety information for tert-Butyl Hypochlorite

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H225:Flammable liquids
H251:Self-heating substances and mixtures
H314:Skin corrosion/irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P235+P410:Keep cool. Protect from sunlight.
P370+P378:In case of fire: Use … for extinction.
P405:Store locked up.
P407:Maintain air gap between stacks/pallets.
P420:Store away from other materials.
P403+P235:Store in a well-ventilated place. Keep cool.
P501:Dispose of contents/container to..…

Computed Descriptors for tert-Butyl Hypochlorite

InChIKey IXZDIALLLMRYOU-UHFFFAOYSA-N

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