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HomeProduct name listTerbufos

Terbufos

  • CAS NO.:13071-79-9
  • Empirical Formula: C9H21O2PS3
  • Molecular Weight: 288.43
  • MDL number: MFCD00055355
  • EINECS: 235-963-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-05-15 10:42:47
Terbufos Structural

What is Terbufos?

Chemical properties

Yellowish liquid. Soluble in alcohol, acetone.

Chemical properties

Terbufos is a colorless to pale yellow liquid.

The Uses of Terbufos

Terbufos is used to control soil pests in maize, sugar beet and vegetables and also nematodes in sugar beet and bananas.

The Uses of Terbufos

Soil insecticide.

Definition

ChEBI: Terbufos is an organic thiophosphate, an organothiophosphate insecticide and an organosulfur compound. It has a role as an EC 3.1.1.7 (acetylcholinesterase) inhibitor, an agrochemical and a nematicide.

General Description

Technical product is a clear, colorless to pale yellow liquid. Used as a soil insecticide.

Air & Water Reactions

Hydrolyzes under alkaline conditions [EPA, 1998]. Insoluble in water.

Reactivity Profile

Organothiophosphates, such as Terbufos, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Terbufos decomposes in the presence of acids or bases .

Hazard

Moderate fire risk. Toxic by ingestion. Cholinesterase inhibitor. Questionable carcinogen.

Health Hazard

Terbufos may be fatal if swallowed, inhaled, or absorbed through the skin. Repeated inhalation or skin contact may progressively increase susceptibility to poisoning.

Fire Hazard

This is a liquid organophosphorus pesticide. Fire may produce irritating or poisonous gases. Hydrolyzes under alkaline conditions.

Agricultural Uses

Insecticide, Nematicide: This insecticide and nematicide is applied at planting time to corn, sugar beets, sorghum, maize, cotton, bananas and cabbage. It controls corn rootworms, wireworms, white grubs, maggots, billbugs and nematodes. Some above-ground pests can be controlled when soil has been treated with terbufos. Terbufos has no residential use. Not approved for use in EU countries. A U.S. EPA restricted use Pesticide (RUP).

Trade name

AC 921000®; ARAGRAN®; CONTRAVEN®; COUNTER®; COUNTER 15G SYSTEMIC INSECTICIDE®; PLYDOX®; TERBUROX®

Potential Exposure

A potential danger to those involved in the manufacture, formulation or application of this organophosphate soil insecticide.

Environmental Fate

Soil. Oxidized in soil to its primary and secondary oxidation products, terbufos sul- foxide and terbufos sulfone, respectively (Bowman and Sans, 1982; Chapman et al., 1982; Wei, 1990). Both metabolites were formed due to micobial activity and chemical oxidation (Chapman et al., 1982). Incubation of terbufos (5 μg/g) in a loamy sand containing Nitrosomonas sp. and Nitrobacter sp. gave terbufos sulfoxide and terbufos sulfone as the primary products. After 2 weeks, the sulfoxide increased the bacterial population >55% and the sulfone increased the fungal population at least 66% (Tu, 1980). The half-life in soil is 9–27 days (Worthing and Hance, 1991).
Chemical/Physical. Terbufos and its degradation products terbufos sulfoxide and ter- bufos sulfone followed first-order disappearance in natural, sterilized natural and distilled water at 20°C. In natural and distilled water, the sulfoxide and su

Metabolic pathway

Terbufos is the S-tertiary butyl homologue of phorate (the S-ethyl homolope). Consequently, the compound is more strongly sorbed to soils; however, the metabolism is essentially the same, with activation via thiooxidation and to a lesser degree oxidative desulfuration being the principal mechanisms. The metabolic routes for terbufos biotransformation have mainly been studied in soils where oxidation to the sulfoxide is rapid and further metabolism to the sulfone quite slow. In common with other phosphorodithioate insecticides, the phosphorodithioate moiety is excreted in mammalian urine as diethyl phosphate, O,O-diethyl phosphorothioate and O,O-diethyl phosphorodithioate and in humans the concentrations of these metabolites have been found useful as indicators of exposure to the insecticide.

Metabolism

The metabolic routes of terbufos are essentially the same in plants, animals, and soils, involving the oxidation of the sulfide group into the sulfoxide, then sulfone, and oxidative desulfuration to the corresponding oxons, followed by hydrolysis to diethyl hydrogen phosphorodithioate, phosphorothioate, and phosphate. DT50 in soil is 9–27 d.

Shipping

UN3018 Organophosphorus pesticides, liquid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1Poisonous materials, Technical Name Required.

Degradation

Terbufos is hydrolysed in strong alkalis (pH>9) and acids (pH﹤2) (PM). Terbufos disappeared rapidly when incubated in distilled water (pH 5.9), natural water (pH 8.7) and sterilised natural water (pH 8.75) with DT50 values of 3.3, 3.2 and 3.5 days, respectively. Terbufos was not converted into the sulfoxide (2) or the sulfone (3) under these conditions. The actual products of hydrolysis were not identified. Terbufos sulfoxide (2) and sulfone (3) were ten to one hundred times more stable than terbufos under the same conditions and there was evidence that, in contrast to terbufos, the hydrolysis was pH dependent (Bowman and Sans, 1982).

Toxicity evaluation

The acute oral LD50 for rats is 1.6mg/kg. Inhalation LC50 (4 h) for rats is 1.2–6.1 μg/L air. ADI is 0.2 μg/kg b.w.

Incompatibilities

Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the presence of strong reducing agents, such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials.

Waste Disposal

In accordance with 40CFR165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Properties of Terbufos

Melting point: -29°C
Boiling point: 69°C (0.01 mmHg)
Density  1.105
vapor pressure  3.46×10-2 Pa (25 °C)
Flash point: 88°C
storage temp.  APPROX 4°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Liquid
color  Colorless, pale
Water Solubility  Insoluble
Merck  13,9233
BRN  1710115
CAS DataBase Reference 13071-79-9(CAS DataBase Reference)
NIST Chemistry Reference Phosphorodithioic acid, s-[(tert-butylthio)methyl] o,o-diethyl ester(13071-79-9)
EPA Substance Registry System Terbufos (13071-79-9)

Safety information for Terbufos

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Environment
GHS09
GHS Hazard Statements H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P262:Do not get in eyes, on skin, or on clothing.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Computed Descriptors for Terbufos

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