SAMARIUM CHLORIDE
Synonym(s):Samarium chloride;Samarium trichloride
- CAS NO.：10361-82-7
- Empirical Formula: Cl3Sm
- Molecular Weight: 256.72
- MDL number: MFCD00011235
- EINECS: 233-797-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:07:02
What is SAMARIUM CHLORIDE?
Chemical properties
OFF-WHITE POWDER
The Uses of SAMARIUM CHLORIDE
Samarium(III) chloride is used for the preparation of samarium metal, which has a variety of uses, notably in magnets. In laboratory Samarium(III) chloride can also be used as a starting point for the preparation of other samarium salts. It is used as infrares absorbing glass, lasers, color television phosphors, magnets, microwave filters. It is used as catalyst in cracking crude petroleum and used as an alloy with cobalt for magnets. It is used as neutron capture masers and have applications in nuclear industry.
Safety Profile
Poison by intraperitoneal and subcutaneous routes. Moderately toxic by ingestion. A skin and eye irritant. When heated to decomposition it emits toxic fumes of Cl-. See also SAMARIUM and RARE EARTHS.
Synthesis
SmCl3 is usually synthesized by the “ammonium chloride” method, which entails the initial formation of
(NH4)2[SmCl5]. This compound can be prepared from common starting materials at a moderate reaction temperature of
230℃ from samarium oxide.
10NH4Cl +Sm2O3→2 (NH )4 2[SmCl5]+ 6NH3+3H2O
Properties of SAMARIUM CHLORIDE
| Melting point: | 686 °C(lit.) |
| Density | 4.46 g/mL at 25 °C(lit.) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Powder |
| color | white to yellow |
| Specific Gravity | 4.465 |
| Water Solubility | Soluble in water. |
| Sensitive | Hygroscopic |
| Merck | 14,8347 |
| Stability: | hygroscopic |
| CAS DataBase Reference | 10361-82-7(CAS DataBase Reference) |
| EPA Substance Registry System | Samarium chloride (SmCl3) (10361-82-7) |
Safety information for SAMARIUM CHLORIDE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H303:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for SAMARIUM CHLORIDE
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