S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
Synonym(s):(S)-(−)-N,N-Bis(2-diphenylphosphinoethyl)-α-methylbenzylamine
- CAS NO.：81510-19-2
- Empirical Formula: C36H37NP2
- Molecular Weight: 545.63
- MDL number: MFCD00233840
- SAFETY DATA SHEET (SDS)
- Update Date: 2022-08-15 17:37:21
What is S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE?
General Description
(S)-(?)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones.
Properties of S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
| Melting point: | 63-65 °C |
| Boiling point: | 632.8±45.0 °C(Predicted) |
| pka | 7.82±0.50(Predicted) |
| optical activity | [α]20/D 4.5±0.7°, c = 1% in acetone |
| BRN | 4608384 |
Safety information for S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
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