(S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
Synonym(s):(S)-(−)-N-Methyl-1-phenylethylamine;(S)-DMBA
- CAS NO.：19131-99-8
- Empirical Formula: C9H13N
- Molecular Weight: 135.21
- MDL number: MFCD00067113
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE?
The Uses of (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
Used to make asymmetric organometallic catalysts (e.g., for conjugate additions to enones).
General Description
(S)-(-)-N,a-Dimethylbenzylamine may be used along with benzaldehyde in the Mannich-type aminoalkylation of 2-naphthol to form 1-((S)-phenyl(((1′S)-1′-phenylethyl)methylamino)methyl)-2-naphthol. This optically active tertiary aminonaphthol can catalyze the enantioselective alkenylation of various aldehyde to generate chiral (E)- allyl alcohols.
Properties of (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
| Melting point: | 116°C (estimate) |
| Boiling point: | 74-76 °C11 mm Hg(lit.) |
| alpha | -72o (C=2 IN CHLOROFORM) |
| Density | 0.928 g/mL at 20 °C(lit.) |
| refractive index | n |
| Flash point: | 143 °F |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| form | clear liquid |
| pka | 9.77±0.10(Predicted) |
| color | Colorless to Almost colorless |
| optical activity | [α]20/D 73±5°, c = 2 in chloroform |
| BRN | 1446867 |
Safety information for (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H312:Acute toxicity,dermal H314:Skin corrosion/irritation H332:Acute toxicity,inhalation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P310:Immediately call a POISON CENTER or doctor/physician. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (S)-(-)-N,ALPHA-DIMETHYLBENZYLAMINE
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