(S)-(-)-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINYL METHYLTMS ETHER
Synonym(s):(S)-α,α-Diphenylprolinol trimethylsilyl ether;(S)-α,α-Diphenylprolinol trimethylsilyl ether, 0.05M solution in toluene;(S)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine;(S)-2-[Diphenyl(trimethylsilanyloxy)methyl]pyrrolidine, 0.05M solution in toluene;(2S)-2-[Diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine
- CAS NO.:848821-58-9
- Empirical Formula: C20H27NOSi
- Molecular Weight: 325.52
- MDL number: MFCD08690083
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is (S)-(-)-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINYL METHYLTMS ETHER?
Chemical properties
Light yellow liquid
The Uses of (S)-(-)-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINYL METHYLTMS ETHER
Organocatalyst for 3-component reactions, and Robinson annulation of α,β-unsaturated aldehydes.
Properties of (S)-(-)-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINYL METHYLTMS ETHER
Boiling point: | 412.7±35.0 °C(Predicted) |
Density | 1.0459 g/mL at 25 °C |
refractive index | n20/D 1.5513 |
Flash point: | 110 °C |
storage temp. | 2-8°C |
form | liquid |
pka | 10.01±0.10(Predicted) |
color | yellow viscous |
optical activity | [α]22/D -50°, c = 1 in chloroform |
λmax | 193nm(lit.) |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
Safety information for (S)-(-)-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINYL METHYLTMS ETHER
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (S)-(-)-ALPHA,ALPHA-DIPHENYL-2-PYRROLIDINYL METHYLTMS ETHER
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
Pyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2R)-
Pyrrolidine, 2-[bis(3,5-dimethylphenyl)[(trimethylsilyl)oxy]methyl]-, (2S)-
(S)-(-)-2-[Bis(3,5-dimethylphenyl)hydroxymethyl]pyrrolidine
S-2-[diphenyl[(triethylsilyl)oxy]Methyl]-Pyrrolidine
S-2-[bis[3,5-bis(trifluoroMethyl)phenyl][[(1,1-diMethylethyl)diMethylsilyl]oxy]Methyl]-Pyrrolidine
S-2-[bis[3,5-bis(3,5-diMethylphenyl]
[(triethylsilyl)oxy]Methyl]-Pyrrolidine
(S)-2-{Bis[3,5-bis(trifluoromethyl)phenyl]hydroxymethyl}pyrrolidine
(S)-[(diphenyl)-t-butyldimethylsiloxymethyl]pyrrolidine
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