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HomeProduct name list(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

Synonym(s):(R,R)-i-Pr-DUPHOS

(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene Structural

What is (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene?

The Uses of (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

It is used as ligands like DuPhos and BPE ligands and are highly efficient privileged ligands.

The Uses of (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

General Description

Optical rotation devation ± 13

Properties of (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

Melting point: 40°C
Boiling point: 502.0±20.0 °C(Predicted)
alpha  +85° (c 1, hexane)
refractive index  n20/D 1.5701
Flash point: >110°(230°F)
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  crystal
color  white
optical activity [α]20/D +103°, c = 1 in chloroform
Water Solubility  Insoluble in water.
Sensitive  Air Sensitive

Safety information for (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene

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