(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
Synonym(s):(R,R)-i-Pr-DUPHOS
- CAS NO.:136705-65-2
- Empirical Formula: C26H44P2
- Molecular Weight: 418.58
- MDL number: MFCD02684549
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene?
The Uses of (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
It is used as ligands like DuPhos and BPE ligands and are highly efficient privileged ligands.
The Uses of (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
General Description
Optical rotation devation ± 13
Properties of (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
Melting point: | 40°C |
Boiling point: | 502.0±20.0 °C(Predicted) |
alpha | +85° (c 1, hexane) |
refractive index | n20/D 1.5701 |
Flash point: | >110°(230°F) |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | crystal |
color | white |
optical activity | [α]20/D +103°, c = 1 in chloroform |
Water Solubility | Insoluble in water. |
Sensitive | Air Sensitive |
Safety information for (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
(R,R)-I-PR-DUPHOS
(+)-1,2-BIS[(2S,5S)-2,5-DIETHYLPHOSPHOLANO]BENZENE
(+)-1,2-BIS[(2S,5S)-2,5-DIMETHYLPHOSPHOLANO]BENZENE
DI-I-BUTYLPHOSPHINE
(R,R)-I-PR-DUPHOS-RH,(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-i-Pr-DUPHOS-Rh
(S,S)-I-PR-DUPHOS,(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene,98+%(S,S)-i-Pr-DUPHOS
(-)-1,2-Bis((2S,5S)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(S,S)-i-Pr-DUPHOS-Rh
(S,S)-I-PR-DUPHOS-RH
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