(R)-(S)-JOSIPHOS
Synonym(s):(R)-(S)-Josiphos;(2R)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS);Josiphos SL-J001-1
- CAS NO.:155806-35-2
- Empirical Formula: C36H44FeP210*
- Molecular Weight: 594.53
- MDL number: MFCD00800284
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is (R)-(S)-JOSIPHOS?
Chemical properties
orange crystalline powder
The Uses of (R)-(S)-JOSIPHOS
It may be used in the preparation of cyclopentadienyliridium complexes, [IrCl(PP)]2 and [IrCp(PP)]. (Cp= cyclopentadienyl; PP= (R)-1-[(SP)-2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine)
What are the applications of Application
(R)-(S)-Josiphos is a chiral diphosphine used for enantioselective synthesis
General Description
sold in collaboration with Solvias AG
Properties of (R)-(S)-JOSIPHOS
Melting point: | ~95 °C (dec.) |
alpha | -360° (c 0.5, CHCl3) |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
form | Crystals or Crystalline Powder |
color | White |
Stability: | store cold |
Safety information for (R)-(S)-JOSIPHOS
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (R)-(S)-JOSIPHOS
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
1,3-BIS(DIMETHYLPHOSPHINO)PROPANE
1,3-BIS(PHOSPHINO)PROPANE
JOSIPHOS SL-J007-1
TRIISOPROPYLPHOSPHINE
JOSIPHOS SL-J006-2,JOSIPHOS SL-J006-1
(R)-(S)-JOSIPHOS
TRIHEXYLPHOSPHINE
JOSIPHOS SL-J002-2
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