(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P
Synonym(s):(1S)-1-[(1R)-1-[Bis[3,5-bis(trifluoromethyl)phenyl]phosphino]ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene (acc to CAS);Walphos SL-W001-1
- CAS NO.：387868-06-6
- Empirical Formula: C46H32F12FeP210*
- Molecular Weight: 930.52
- MDL number: MFCD04112740
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-01-11 10:46:38
![(R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P Structural](https://img.chemicalbook.in/CAS/GIF/387868-06-6.gif)
What is (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P?
Chemical properties
Orange powder
The Uses of (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P
Walphos SL-W001-1, in the presence of a ruthenium catalyst may be used as a ligand in the following processes:
- Asymmetric hydrogenation of IPCA-D, a cinnamic acid derivative.
- Addition of 3,5-difluorophenylketimine to 4-methoxyphenylboronic acid to form the corresponding tertiary substituted cyclic sulfamate derivative with high enantioselctivity.2
General Description
The product is an air-stable and non-hygroscopic Solvias chiral phosphine ligand.
Safety information for (R)-(-)-1-[(R)-2-(2'-DIPHENYLPHOSPHINOPHENYL)FERROCENYL]ETHYLDI(BIS-3,5-CF3-PH2)P
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
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![(R)-1-[(R)-2-[2-[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]PHENYL]FERROCENYL]-ETHYLBIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]PHOSPHINE](https://img.chemicalbook.in/CAS/GIF/494227-30-4.gif)
![(R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]FERROCENYL]ETHYLDI(3,5-XYLYL)PHOSPHINE](https://img.chemicalbook.in/CAS/GIF/494227-31-5.gif)
![(R)-1-[(R)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-FERROCENYL]ETHYLDIPHENYLPHOSPHINE](https://img.chemicalbook.in/CAS/GIF/388079-58-1.gif)
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