(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
Synonym(s):(1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS);Josiphos SL-J004-1
- CAS NO.：158923-09-2
- Empirical Formula: C36H44FeP210*
- Molecular Weight: 594.53
- MDL number: MFCD00800280
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
![(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Structural](https://img.chemicalbook.in/CAS/GIF/158923-09-2.gif)
What is (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE?
Chemical properties
Red crystal
The Uses of (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:
- To prepare iridium metal complex (IrIJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
- In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.
Reactions
1. Ligand for asymmetric hydroformylation reactions
2. Ligand for asymmetric intramolecular amide arylation
3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates
4. Ligand for enantioselective synthesis of vicinal dialkyl arrays
5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones
.
General Description
sold in collaboration with Solvias AG
Properties of (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
| alpha | -100° ±5° (c 0.5, CHCl3) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Powder |
| color | orange |
Safety information for (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
New Products
COBALT AAS SOLUTION HYDROXYLAMINE HYDROCHLORIDE SOLUTION 10% THOMALIT BLUE LITMUS PAPER 1 BOX SILVER NITRATE N/10 CVS GLASS BEADS 3.5 TO 4.5 MM POTASSIUM AAS SOLUTION Azithromycin Imp D Atracurium Besylate EP Impurity C Ceftaroline fosamil Acetate Hydrate Clarithromycin EP impurity F Clarithromycin EP Impurity D Clindamycin BRelated products of tetrahydrofuran
![(S)-1-[(1R)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE](https://img.chemicalbook.in/CAS/GIF/162291-01-2.gif)
You may like
-
![(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine CAS 158923-09-2](https://img.chemicalbook.in//Content/image/CP5.jpg)
(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine CAS 158923-09-2View Details
158923-09-2 -
Atracurium Besylate EP Impurity CView Details
86293-35-8 -
Azithromycin EP Impurity CView Details
620169-47-3 -
Azithromycin Imp DView Details
612069-26-8 -
Ceftaroline fosamil Acetate HydrateView Details
400827-55-6 -
Clarithromycin EP Impurity FView Details
128940-83-0 -
Clarithromycin EP Impurity DView Details
101666-68-6 -
Clindamycin Impurity BView Details
18323-43-8
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.