Potassium trimethylsilanolate
Synonym(s):Trimethylsilanol potassium salt
- CAS NO.：10519-96-7
- Empirical Formula: C3H9KOSi
- Molecular Weight: 128.29
- MDL number: MFCD00013421
- EINECS: 234-062-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:57
What is Potassium trimethylsilanolate?
The Uses of Potassium trimethylsilanolate
Potassium trimethylsilanolate can be used as a reagent in the:
- Hydrolysis of nitriles to primary amides.
- Conversion of esters to carboxylic acids, and dialkyl phosphonates to their monoalkyl phosphonates.
- Synthesis of E-alkenes, and nitrocefin.
It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.
Purification Methods
Recrystallise it from H2O and dry it at 100o/1-2mm. [Hyde et al. J Am Chem Soc 75 5615 1953, IR: Tatlock & Rochow J Org Chem 17 1555 1952, Beilstein 4 IV 3992.]
Properties of Potassium trimethylsilanolate
| Melting point: | 135-138 °C (lit.) |
| Density | 0.91 |
| Flash point: | -14°C (7°F) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | DMSO (Springly), Methanol (Slightly) |
| form | powder |
| Specific Gravity | 0.91 |
| color | White |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 3560282 |
| EPA Substance Registry System | Silanol, trimethyl-, potassium salt (10519-96-7) |
Safety information for Potassium trimethylsilanolate
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Potassium trimethylsilanolate
| InChIKey | LBKJNHPKYFYCLL-UHFFFAOYSA-N |
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product: Potassium trimethylsilanolate
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