PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
- CAS NO.：185812-86-6
- Empirical Formula: C24H56Br2P2Pd2
- Molecular Weight: 779.31
- MDL number: MFCD04114019
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-21 22:41:43
What is PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE?
Chemical properties
Greenish blue
The Uses of PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
Coupling reactions. Will activate aryl chloride and sterically hindered or electron rich aryl/vinyl bromides and iodides. Especially active in difficult aminations.Di-μ-bromobis(tri-tert-butylphosphine)dipalladium(I) is used as a catalyst for Suzuki coupling, Negishi coupling and Buchwald-hartwig amination reactions. It is used as a catalyst for C-C, C-N and C-S bond formation, gamma-arylation of alfa,beta-unsaturated esters and diastereoselective arylation of 4-substituted cyclohexyl esters. It is also involved in aromatic halide substitution reactions.
What are the applications of Application
Bromo(tri-tert-butylphosphine)palladium(I) dimer is a versatile catalyst for aromatic substitution reactions
Properties of PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| form | crystal |
| color | dark-green |
| Water Solubility | Soluble in benzene and tolueneSoluble in tetrahydrofuran, toluene, dichloromethane and chloroform. Insoluble in alcohols and water. |
| Sensitive | Air Sensitive |
Safety information for PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
| Signal word | Danger |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for PALLADIUM (I) TRI-TERT-BUTYLPHOSPHINE BROMIDE
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
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