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HomeProduct name listMETHYL VALERATE

METHYL VALERATE

Synonym(s):Methyl pentanoate

  • CAS NO.:624-24-8
  • Empirical Formula: C6H12O2
  • Molecular Weight: 116.16
  • MDL number: MFCD00009478
  • EINECS: 210-838-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-19 17:35:41
METHYL VALERATE Structural

What is METHYL VALERATE?

Description

Methyl pentanoate, commonly known as methyl valerate, is the methyl ester of pentanoic acid (valeric acid) with a fruity odor.
Methyl pentanoate is commonly used in fragrances, beauty care, soap, laundry detergents at levels of 0.1 – 1 % .
In a very pure form ( greater than 99.5 % ) it is used as a plasticizer in the manufacture of plastics.
It is also used as an insecticide.

Chemical properties

clear colorless liquid

Chemical properties

Methyl valerate has a pungent, green-fruity odor that is apple- and pineapple-like with a corresponding flavor at 1 0 - 5 0 ppm. May be prepared by direct esterification of the valeric acid with methanol in the presence of concentrated H2S04; note: this ester hydrolyzes readily.

Chemical properties

Methyl valerate has a pungent, green-fruity odor, apple and pineapple-like. It has a similar flavor at 10 to 50 ppm

Occurrence

Reported found in small amounts in the essential oil from the fruits of Ananas sativus Schult. Also reported present in apple, coffee, honey, kiwi, melon, papaya, pineapple, strawberry, tea, wine, blackberry, baked potato, olive, starfruit, passion fruit, soursop, Bourbon vanilla, mountain papaya and naranjilla fruit.

The Uses of METHYL VALERATE

Methyl valerate can be used:

  • In the preparation of lankacidin C 8-valerate.
  • As a reactant to synthesize bis(2,2,2-trifluoroethyl) 2-oxoalkylphosphonates.
  • As a substrate in the fluorination reactions of unactivated C(sp3)H bonds using decatungstate photocatalyst and N-fluorobenzenesulfonimide.

Preparation

By direct esterification of valeric acid with methanol in the presence of concentrated H2SO4. Note: This ester hydrolyzes readily

What are the applications of Application

Methyl valerate is primarily used in flavor compositions, although it occasionally finds application in certain phases of perfumery (masking, household products of certain type, etc.).
Its Apple-like character is useful in fruit complexes where diffusive power is desirable (chewing gum, etc.) and it performs very well in Pineapple or fantasy flavors.

Aroma threshold values

Detection: 20 to 89 ppb

Taste threshold values

Taste characteristics at 20 ppm: sweet, ripe, fruity with sweaty, dairy and cheesy nuance

Synthesis Reference(s)

Journal of the American Chemical Society, 97, p. 1180, 1975 DOI: 10.1021/ja00838a036

General Description

Clear colorless to yellowish oily liquid.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

METHYL VALERATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. METHYL VALERATE reacts with oxidizing agents, bases and acids.

Fire Hazard

METHYL VALERATE is flammable.

Flammability and Explosibility

Flammable

Properties of METHYL VALERATE

Melting point: -91°C
Boiling point: 128 °C (lit.)
Density  0.875 g/mL at 25 °C (lit.)
vapor pressure  19.33hPa at 20℃
refractive index  n20/D 1.397(lit.)
FEMA  2752 | METHYL VALERATE
Flash point: 72 °F
storage temp.  Flammables area
solubility  5g/l
form  Liquid
color  Clear colorless
Specific Gravity 0.892 (20/4℃)
Odor at 1.00 % in dipropylene glycol. sweet green fruity apple pineapple nutty
Odor Threshold 0.0022ppm
Water Solubility  3.5g/L at 20℃
JECFA Number 159
BRN  1741905
Dielectric constant 4.3(19℃)
CAS DataBase Reference 624-24-8(CAS DataBase Reference)
EPA Substance Registry System Methyl valerate (624-24-8)

Safety information for METHYL VALERATE

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H317:Sensitisation, Skin
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

Computed Descriptors for METHYL VALERATE

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