METHYL NONANOATE
Synonym(s):Methyl pelargonate;Nonanoic acid methyl ester
- CAS NO.:1731-84-6
- Empirical Formula: C10H20O2
- Molecular Weight: 172.26
- MDL number: MFCD00009569
- EINECS: 217-052-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-25 18:01:17
What is METHYL NONANOATE?
Description
Methyl nonanoate has a wine and coconut-like odor. Below 10 ppm, it has a sweet, coconut-like flavor. May be synthesized by heating pelargonic acid with methyl alcohol in the presence of concentrated sulfuric acid and subsequent rectification; or by hydrogenation of 1,5-octadien-carboxylic acid methyl ester using palladium chloride in methanol solution.
Chemical properties
Clear colorless liquid
Chemical properties
Methyl nonanoate has a wine and coconut-like odor. Below 10 ppm, it has a sweet, coconut-like flavor
Occurrence
Reported found in orris derivatives, apple, banana, blackberry, baked potato, blue cheeses, beef fat, hop oil, white wine, starfruit, prickly pear, wort, Bourbon vanilla, mountain papaya, spineless monkey orange and rooibus tea (Aspalathus linearis)
The Uses of METHYL NONANOATE
Methyl nonanoate (Methyl pelargonate) was used in the synthesis of vanillyl nonanoate, a model compound of capsinoids.
The Uses of METHYL NONANOATE
Perfumes, flavors, reference standard for gaschromatography, intermediate in organic synthesis,medical research.
What are the applications of Application
Methyl nonanoate is a useful biochemical for proteomics research
Definition
ChEBI: A fatty acid methyl ester obtained from the formal condensation of methanol and nonanoic acid; a colourless liquid with a fruity odour, used in perfumes and flavours, and for medical research.
Preparation
By heating pelargonic acid with methyl alcohol in the presence of concentrated sulfuric acid and subsequent rectification; or by hydrogenation of 1,5-octadien-carboxylic acid methyl ester using palladium chloride in methanol solution.
Taste threshold values
Taste characteristics at 1 to 10 ppm: winey, waxy, green, celery and pear with an unripe fruit nuance.
Synthesis Reference(s)
The Journal of Organic Chemistry, 54, p. 1213, 1989 DOI: 10.1021/jo00266a046
Tetrahedron Letters, 22, p. 4279, 1981 DOI: 10.1016/S0040-4039(01)82933-6
Properties of METHYL NONANOATE
Melting point: | 30°C |
Boiling point: | 213-214 °C (lit.) |
Density | 0.875 g/mL at 25 °C (lit.) |
refractive index | n |
FEMA | 2724 | METHYL NONANOATE |
Flash point: | 184 °F |
storage temp. | room temp |
solubility | Chloroform (Sparingly), Methanol (Slightly) |
form | Liquid |
color | Clear colorless |
Odor | at 100.00 %. sweet fruity pear waxy tropical wine |
JECFA Number | 179 |
BRN | 1754521 |
CAS DataBase Reference | 1731-84-6(CAS DataBase Reference) |
EPA Substance Registry System | Nonanoic acid, methyl ester (1731-84-6) |
Safety information for METHYL NONANOATE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H227:Flammable liquids |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use … for extinction. P403+P235:Store in a well-ventilated place. Keep cool. |
Computed Descriptors for METHYL NONANOATE
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile Diclofenac Potassium Ornidazole IP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Aceclofenac IP/BP/EP Nimesulide BP SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION Methylcobalamin (vitamin B12) SODIUM METHYL PARABEN SODIUM VALPROATE Racecadotril XANTHAN GUMRelated products of tetrahydrofuran
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