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HomeProduct name listMETHYL ALPHA-BROMOPHENYLACETATE

METHYL ALPHA-BROMOPHENYLACETATE

  • CAS NO.:3042-81-7
  • Empirical Formula: C9H9BrO2
  • Molecular Weight: 229.07
  • MDL number: MFCD00013535
  • EINECS: 608-480-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
METHYL ALPHA-BROMOPHENYLACETATE Structural

What is METHYL ALPHA-BROMOPHENYLACETATE?

Chemical properties

Light yellow to yellow liquid

The Uses of METHYL ALPHA-BROMOPHENYLACETATE

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.

Synthesis Reference(s)

Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6

General Description

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.

Properties of METHYL ALPHA-BROMOPHENYLACETATE

Boiling point: 113 °C3 mm Hg(lit.)
Density  1.46 g/mL at 20 °C(lit.)
refractive index  n20/D 1.554
Flash point: >230 °F
storage temp.  2-8°C
form  clear liquid
color  Colorless to Light orange to Yellow
BRN  1102743

Safety information for METHYL ALPHA-BROMOPHENYLACETATE

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for METHYL ALPHA-BROMOPHENYLACETATE

InChIKey NHFBYYMNJUMVOT-UHFFFAOYSA-N

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