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HomeProduct name listEthyl α-bromophenylacetate

Ethyl α-bromophenylacetate

  • CAS NO.:2882-19-1
  • Empirical Formula: C10H11BrO2
  • Molecular Weight: 243.1
  • MDL number: MFCD00013536
  • EINECS: 220-735-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
Ethyl α-bromophenylacetate Structural

What is Ethyl α-bromophenylacetate?

The Uses of Ethyl α-bromophenylacetate

ETHYL ALPHA-BROMOPHENYLACETATE is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate.

The Uses of Ethyl α-bromophenylacetate

α-Bromobenzeneacetic acid ethyl ester is used as an alkyl halide initiator in controlled/living radical polymerization of styrene and methyl methacrylate.

What are the applications of Application

Ethyl α-bromophenylacetate (EBPA) may be used to synthesize α-ethoxycarbonyl-N,α-diphenylnitrone.
EBPA may be used as an initiator for the following:
polymerization of dimethyl(methacryloyloxymethyl) phosphonate
polymerization of methyl methacrylate (MMA)
polymerization of trimethylolpropane triacrylate(TMPTA)

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 4067, 1972 DOI: 10.1016/S0040-4039(01)94239-X

Precautions

Moisture sensitive. Store away from oxidizing agents, air and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Properties of Ethyl α-bromophenylacetate

Boiling point: 89-92 °C/0.9 mmHg (lit.)
Density  1.389 g/mL at 25 °C (lit.)
refractive index  n20/D >1.5390(lit.)
Flash point: >230 °F
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  Liquid
color  Clear colorless to yellow
Water Solubility  Not miscible or difficult to mix in water.
Sensitive  Moisture Sensitive
CAS DataBase Reference 2882-19-1(CAS DataBase Reference)
EPA Substance Registry System Ethyl .alpha.-bromophenylacetate (2882-19-1)

Safety information for Ethyl α-bromophenylacetate

Signal word Danger
Pictogram(s)
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H314:Skin corrosion/irritation
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for Ethyl α-bromophenylacetate

InChIKey BKTKLDMYHTUESO-UHFFFAOYSA-N

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