METHYL 10-UNDECENOATE
Synonym(s):10-Undecenoic acid methyl ester;Undecylenic acid methyl ester
- CAS NO.：111-81-9
- Empirical Formula: C12H22O2
- Molecular Weight: 198.3
- MDL number: MFCD00016689
- EINECS: 203-910-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is METHYL 10-UNDECENOATE?
Chemical properties
Colorless liquid; oily aroma.
The Uses of METHYL 10-UNDECENOATE
Methyl 10-undecenoate, unsaturated fatty acid ester, is used to modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane for the preparation of silicone hollow nano/microstructures in water.
The Uses of METHYL 10-UNDECENOATE
Methyl 10-undecenoate is an unsaturated fatty acid ester that can be used as a substrate:
- To prepare bifunctional polymer precursors via hydroformylation reaction.
- To synthesize α,ω-ester amides via aminocarbonylation in the presence of palladium catalyst.
- To modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane, for the preparation of silicone hollow nano/microstructures in water by hydrosilylation reaction.
Definition
ChEBI: A fatty acid methyl ester of 10-undecenoic acid.
Aroma threshold values
Medium strength odor, fatty type
Synthesis Reference(s)
The Journal of Organic Chemistry, 54, p. 3015, 1989 DOI: 10.1021/jo00274a010
Tetrahedron, 52, p. 915, 1996 DOI: 10.1016/0040-4020(95)00950-7
Synthetic Communications, 3, p. 281, 1973 DOI: 10.1080/00397917308065917
General Description
Methyl 10-undecenoate is the chain stopper in the polymerization of long-chain aliphatic α,ω-diene through acyclic diene metathesis (ADMET). This helps in tuning the molecular weight of the resulting polyester in a range varying from 10 to 45 kDa.
Flammability and Explosibility
Non flammable
Properties of METHYL 10-UNDECENOATE
| Melting point: | 26-27℃ |
| Boiling point: | 245 °C (lit.) |
| Density | 0.882 g/mL at 25 °C (lit.) |
| vapor pressure | 2.1hPa at 25℃ |
| refractive index | n |
| FEMA | 4253 | METHYL 10-UNDECENOATE |
| Flash point: | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | H2O: insoluble |
| form | clear liquid |
| color | Colorless to Light yellow |
| Specific Gravity | 0.882 |
| Odor | at 100.00 %. fatty waxy citrus earthy fungal rose floral |
| Water Solubility | 794μg/L at 20℃ |
| JECFA Number | 1639 |
| CAS DataBase Reference | 111-81-9(CAS DataBase Reference) |
| EPA Substance Registry System | 10-Undecenoic acid, methyl ester (111-81-9) |
Safety information for METHYL 10-UNDECENOATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07  Environment GHS09 |
| GHS Hazard Statements |
H410:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P273:Avoid release to the environment. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
Computed Descriptors for METHYL 10-UNDECENOATE
METHYL 10-UNDECENOATE manufacturer
Acme Synthetic Chemicals
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Phone:+919833260962
Whatsapp: +91- 9833260962
product: Methyl 10-undecenoate 98%
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