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HomeProduct name listMethallyl alcohol

Methallyl alcohol

Synonym(s):β-Methallyl alcohol;‘Isobutenol’

  • CAS NO.:513-42-8
  • Empirical Formula: C4H8O
  • Molecular Weight: 72.11
  • MDL number: MFCD00004737
  • EINECS: 208-161-0
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-03-14 15:18:33
Methallyl alcohol  Structural

What is Methallyl alcohol ?

Description

Methallyl alcohol is a colorless liquid with a pungent odor. Molecular weight= 72.12;Boiling point=114℃; Flash point=33℃. Hazard Identification (based on NFPA-704 M Rating System): Health 2, Flammability 3, Reactivity 0. Slightly soluble in water.

Chemical properties

CLEAR COLOURLESS LIQUID

The Uses of Methallyl alcohol

2-Methyl-2-propen-1-ol (MePro) attaches to hemicellulose acetylated galactoglucomannan (AcGGM) backbone providing it with pendant sites that allow subsequent cross-linking and hydrogel formation.

Production Methods

Methallyl alcohol is prepared by hydrolysis of methallyl chloride in a 10 wt% aqueous sodium hydroxide solution. Pure methallyl alcohol can be obtained by methanolysis of methallyl acetate in the presence of catalytic amounts of bases. Methallyl alcohol is used in the preparation of polymerizable esters.

General Description

A colorless liquid with a sharp pungent odor. Soluble in water and floats on water. Moderately toxic by ingestion and is an irritant to eyes and skin. Used in the chemical process industry.

Air & Water Reactions

Highly flammable and soluble in water.

Reactivity Profile

Methallyl alcohol may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.

Health Hazard

Exposure can cause irritation of eyes, nose and throat.

Potential Exposure

Used as an intermediate in organic synthesis

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

storage

Color Code—Red: Flammability Hazard: Store in a flammable liquid storage area or approved cabinet away from ignition sources and corrosive and reactive materials. Prior to working with this chemical you should be trained on its proper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from oxidizers and other incompatible materials. Metal containers involving the transfer of this chemical should be grounded and bonded. Drums must be equipped with self-closing valves. Sources of ignition, such as smoking and open flames, are prohibited where this chemical is used, handled, or stored in a manner that could create a potential fire or explosion hazard.

Shipping

This compound requires a shipping label of “FLAMMABLE LIQUID.” It falls in Hazard Class 3 and Packing Group II.

Incompatibilities

Forms explosive mixture with air. Incompatible with strong acids, caustics, aliphatic amines, isocyanates, DMSO, oxidizers.

Properties of Methallyl alcohol

Melting point: -50 °C
Boiling point: 113-115 °C(lit.)
Density  0.857 g/mL at 25 °C(lit.)
refractive index  n20/D 1.426(lit.)
Flash point: 92 °F
storage temp.  Flammables area
solubility  Chloroform (Slightly), Methanol (Slightly)
form  clear liquid
pka 14.49±0.10(Predicted)
Specific Gravity 0.8515
color  Colorless to Almost colorless
Water Solubility  11 g/100 mL
BRN  969226
Stability: Light Sensitive
CAS DataBase Reference 513-42-8(CAS DataBase Reference)
NIST Chemistry Reference 2-Propen-1-ol, 2-methyl-(513-42-8)
EPA Substance Registry System Methallyl alcohol (513-42-8)

Safety information for Methallyl alcohol

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Methallyl alcohol

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