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HomeProduct name listm-Phenylenediamine

m-Phenylenediamine

Synonym(s):1,3-Benzenediamine;1,3-Diaminobenzene;1,3-Phenylenediamine;MPDA

  • CAS NO.:108-45-2
  • Empirical Formula: C6H8N2
  • Molecular Weight: 108.14
  • MDL number: MFCD00007799
  • EINECS: 203-584-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-25 16:21:11
m-Phenylenediamine Structural

What is m-Phenylenediamine?

Chemical properties

Grey crystal granule

Chemical properties

m-Phenylenediamine is a colorless to white crystalline substance that turns red upon exposure to air

The Uses of m-Phenylenediamine

The appearance of the high purity of the m-phenylenediamine is snow white flake solid used as a synthetic electronic grade polyimide material and epoxy resin curing agent.

The Uses of m-Phenylenediamine

1,3-Phenylenediamine is used in the foaming-type hair dye composition.

The Uses of m-Phenylenediamine

m-Phenylenediamine is used in the foaming-type hair dye composition. It is used as a synthetic electronic grade polyimide material and epoxy resin curing agent. It is used also block polymers, textile fibers, urethanes, petroleum additives, rubber chemicals, in corrosion inhibitors, in photography, as reagent for gold & bromine.

Definition

ChEBI: 1,3-phenylenediamine is a phenylenediamine taht is benzene substituted at positions 1 and 3 with amino functions.

Synthesis Reference(s)

Journal of the American Chemical Society, 102, p. 6182, 1980 DOI: 10.1021/ja00539a054
The Journal of Organic Chemistry, 37, p. 930, 1972 DOI: 10.1021/jo00972a002

General Description

Colorless or white colored needles that turn red or purple in air. Melting point 64-66 C. Density 1.14 g / cm3. Flash point 280 F. May irritate skin and eyes. Toxic by skin absorption, inhalation or ingestion. Used in aramid fiber manufacture, as a polymer additive, dye manufacturing, as a laboratory reagent, and in photography.

Air & Water Reactions

Soluble in water [Merck].

Reactivity Profile

m-Phenylenediamine an aromatic amine, neutralizes acids, acid chlorides, acid anhydrides and chloroformates in exothermic reactions to form salts. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Incompatible with oxidizing agents .

Fire Hazard

m-Phenylenediamine is combustible. Dust may form explosive mixtures in air

Flammability and Explosibility

Non flammable

Safety Profile

Suspected carcinogen with experimental tumorigenic and teratogenic data. Poison by ingestion, intravenous, subcutaneous, and intraperitoneal routes. Mildly toxic by skin contact. Mutation data reported. Combustible when exposed to heat or flame. A hair dye ingredtent. When heated to decomposition it emits toxic fumes of NOx. See also other phenylenediamine entries and AMINES.

Potential Exposure

Used in making various dyes; as a curing agent for epoxy resin; rubber, textile fibers; urethanes, corrosion inhibitors; adhesives; in photographic and analytical procedures and processes.

Carcinogenicity

"Occupational exposure to m-PDA may occur through inhalation and dermal contact with this compound at workplace where m-PDA is produced or used. The general population may be exposed to m-PDA via dermal contact with consumer products containing this compound."An IARC Working Group concluded, on the basis of lack of human data and inadequate animal data, that m-PDA was not classifiable (Group 3) as to its carcinogenicity to humans.

Metabolic pathway

By the perfused rat liver, 1,3-diaminobenzene (MPD) is metabolized to three identified N-acetylated derivatives N-acetyl-1,3-diaminobenzene, N,N'- diacetyl-1,3-diaminobenzene, and N,N'-diacetyl-2,4- diaminophenol which are identical to the metabolites excreted in rat urine.

Shipping

UN1673 Phenylenediamines (o-, m-, p-), Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Purify the diamine by distillation under a vacuum followed by recrystallisation from EtOH (rhombs) and if necessary redistillation. It should be protected from light; otherwise it darkens rapidly. [Neilson et al. J Chem Soc 371 1962, IR: Katritzky & Jones J Chem Soc 3674, 2058 1959, UV: Forbes & Leckie Can J Chem 36 1371 1958.] The hydrochloride has m 277-278o, and the bis-4-chlorobenzenesulfonyl derivative has m 220-221o from H2O (214-215o, from MeOH/H2O) [Runge & Pfeiffer Chem Ber 90 1737 1957]. The acetate has m 191o. [Beilstein 13 IV 79.]

Incompatibilities

Dust may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid chlorides; acid anhydrides; chloroformates. Heat and light contribute to instability. Keep away from metals.

Waste Disposal

Controlled incineration whereby oxides of nitrogen are removed from the effluent gas by scrubber, catalytic or thermal device.

Properties of m-Phenylenediamine

Melting point: 64-66 °C
Boiling point: 282-284 °C
Density  1,139 g/cm3
vapor density  3.7 (vs air)
vapor pressure  0.62 mm Hg ( 100 °C)
refractive index  1.6339
Flash point: >230 °F
storage temp.  Store below +30°C.
solubility  350g/l
form  pellets
pka 5.11, 2.50(at 20℃)
color  Yellow to light tan or brown gray
PH 8 (100g/l, H2O, 20℃)
Water Solubility  350 g/L (25 ºC)
Sensitive  Air Sensitive
Merck  14,7283
BRN  471357
Exposure limits ACGIH: TWA 0.1 mg/m3
Stability: AIR SENSITIVE
CAS DataBase Reference 108-45-2(CAS DataBase Reference)
NIST Chemistry Reference 1,3-Benzenediamine(108-45-2)
IARC 3 (Vol. 16, Sup 7) 1987
EPA Substance Registry System 1,3-Phenylenediamine (108-45-2)

Safety information for m-Phenylenediamine

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
ghs
Health Hazard
GHS08
ghs
Environment
GHS09
GHS Hazard Statements H317:Sensitisation, Skin
H319:Serious eye damage/eye irritation
H341:Germ cell mutagenicity
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for m-Phenylenediamine

InChIKey WZCQRUWWHSTZEM-UHFFFAOYSA-N

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