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HomeProduct name listLithium azide

Lithium azide

Synonym(s):Lthium triazide

  • CAS NO.:19597-69-4
  • Empirical Formula: LiN3
  • Molecular Weight: 48.96
  • MDL number: MFCD00041956
  • EINECS: 243-177-1
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-10 13:17:07
Lithium azide Structural

What is Lithium azide?

Chemical properties

clear colorless solution

The Uses of Lithium azide

Lithium azide is the lithium salt of Hydrazoic acid and is used to carry out azidolysis reactions (in Acetonitrile), as well as ring opening reactions of aromatics such as Styrene oxide (S687795).

Purification Methods

Digest ~1g with 15mL of 96% EtOH at 35o, filter and dry it in air at temperatures below 80o. Store it in a cool place and treat it as potentially explosive. Its solubility in H2O is 66.4% at16o, and 20.26% at16o in EtOH. [Hofmann-Bang Acta Chem Scand 11 581 1957, Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 581 1963.]

Properties of Lithium azide

Melting point: decomposes at 115–298℃ [CRC10]
Boiling point: 103 °C
Density  1.088 g/mL at 25 °C
solubility  soluble in Water
form  Liquid
color  Clear colorless
Water Solubility  g/100g H2O: 61.3 (0°C), 67.2 (20°C), 86.6 (60°C) [LAN05]
EPA Substance Registry System Lithium azide (Li(N3)) (19597-69-4)

Safety information for Lithium azide

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H311:Acute toxicity,dermal
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for Lithium azide

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