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HomeProduct name listL-BORNYL ACETATE

L-BORNYL ACETATE

Synonym(s):endo-(1S)-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate

  • CAS NO.:5655-61-8
  • Empirical Formula: C12H20O2
  • Molecular Weight: 196.29
  • MDL number: MFCD00867808
  • EINECS: 227-101-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-20 11:41:24
L-BORNYL ACETATE Structural

What is L-BORNYL ACETATE?

Chemical properties

L-Bornyl acetate is a clear colorless liquid or crystalline mass, melting at 29℃. (when pure). (the inactive all-form does not crystallize). Sp.Gr. 0.98. B.P. 226℃. Very slightly soluble in water, almost insoluble in Propylene Glycol and Glycerin, soluble in alcohol and oils. Sweet herbaceous-piney odor with a balsamic undertone, Reminiscent of Pme Needles.

Chemical properties

Colorless solid; sweet herbaceous aroma.

Occurrence

Reported found in carrot, coriander, spike lavender, pine needle, rosemary, sage and valerian root.

The Uses of L-BORNYL ACETATE

(?)-Bornyl acetate can be used:

  • As a key intermediate in the preparation of camphor.
  • To prepare (?)-englerin A, an anti-cancer agent.

The Uses of L-BORNYL ACETATE

Suggested for use in Fougeres, Chypres, Lavender colognes, Room spray fragrances, Bathoils, Pine fragrances, etc. lts odor is richer than that of the iso-Bomyl acetate. Finds some use in flavor compositions for Fruit and Spice flavorings. The concentration will usuallybe about 70-80 ppm in the finished product.

Preparation

By esterification of laevo-Bomeol. On account of its high melting point it can also be isolated from a mixture of isomers. dextro-Bornyl acetate is produced from dextro-Borneol (esterification with Acetic anhydride and Sodium acetate).

Aroma threshold values

Medium strength odor, balsamic type.

General Description

Produced and qualified by HWI pharma services GmbH.
Exact content by quantitative NMR can be found on the certificate.

Flammability and Explosibility

Non flammable

Properties of L-BORNYL ACETATE

Melting point: 27°C
Boiling point: 223-224 °C(lit.)
Density  0.984g/mL20°C
vapor pressure  0.6 mm Hg ( 20 °C)
refractive index  n20/D 1.463
FEMA  4080 | L-BORNYL ACETATE
Flash point: 184 °F
storage temp.  -20°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  Liquid
color  Clear colorless
Odor at 100.00 %. sweet balsamic woody fresh pine needle herbal
optical activity [α]20/D 46±2°, c = 1% in ethanol
Water Solubility  62.6mg/L at 20℃
Merck  14,1339
JECFA Number 1864
BRN  2502036
CAS DataBase Reference 5655-61-8(CAS DataBase Reference)
EPA Substance Registry System Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, (1S,2R,4S)- (5655-61-8)

Safety information for L-BORNYL ACETATE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H227:Flammable liquids
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378:In case of fire: Use … for extinction.
P403+P235:Store in a well-ventilated place. Keep cool.
P501:Dispose of contents/container to..…

Computed Descriptors for L-BORNYL ACETATE

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