Iodosulfuron methyl sodium
Synonym(s):Methyl 4-iodo-2-[3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)ureidosulfonyl]benzoate sodium salt
- CAS NO.:144550-36-7
- Empirical Formula: C14H13IN5NaO6S
- Molecular Weight: 529.2
- MDL number: MFCD06636642
- EINECS: 236-293-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-21 22:41:43
What is Iodosulfuron methyl sodium?
The Uses of Iodosulfuron methyl sodium
Iodosulfuron Methyl Ester Sodium is used as a pesticide.
Agricultural Uses
At a rate of 2.5–10 g a.i. ha−1, iodosulfuron‐methyl‐sodium (AE F115008) controls more than 50 different broadleaf weed species, including some very competitive weeds that cause a substantial reduction of cereal productivity, for example, G. aparine, M. chamomilla, S. media, Raphanus ssp., Cirsium arvense, and Lamium ssp. While the application of iodosulfuronmethyl‐ sodium at the lower end of the suggested use rate is usually sufficient for control of broadleaf weeds, a higher rate is needed for consistent grass weed control. Major grass weeds controlled with a 7.5–10 g a.i. ha−1 dose rate applied at the three‐leaf stage up to the end of tillering are Agrostis gigantea, A. spica‐venti, Lolium multiflorum, L. perenne, L. persicum, L. rigidum, Phalaris brachystachys, P. canariensis, P. paradoxa, P. annua, and P. trivialis.
When introduced in 1999, iodosulfuron‐methyl‐sodium was the first “safened” sulfonylurea herbicide available commercially and has been marketed by Bayer CropScience for use both in cereals and maize. A “safener,” such as mefenpyr‐ diethyl, is a chemical that, when applied to crop plants, reduces the injury caused by herbicides to an acceptable level. Ideally, a safener does not reduce activity against the target weeds. When a series of experiments was conducted to compare the behavior of iodosulfuron‐methyl‐sodium with and without mefenpyr‐diethyl as safener, the results suggested that the safener acted via a specific catalytic enhancement of herbicide degradation in cereals, but not in target weeds such as wild oat.
In cereals, iodosulfuron‐methyl‐sodium is available commercially under the trade name “Hussar” as a straight product in a 1 : 3 ratio with mefenpyr‐diethyl as safener. The compound is also sold in various combinations with other mixing partners, such as “Hussar® OF” (+ fenoxaprop‐p‐ethyl + mefenpyr‐diethyl), “Sekator®/Chekker®” (+ amidosulfuron + mefenpyr‐diethyl), “Cossack®” (+ mesosulfuron + mefenpyrdiethyl), and “Atlantis®” (+ mesosulfuron + mefenpyr‐diethyl).
Properties of Iodosulfuron methyl sodium
Melting point: | 152° |
storage temp. | 0-6°C |
solubility | Solubility in organic solvents (g/l at 20 °C) Acetonitrile 52 Ethyl acetate 23 n‐Heptane 0.001 Methanol 12 2‐Propanol 4.4 Toluene 2.1 |
form | neat |
pka | Dissociation constant (pKa at 20 °C) 3.22 (Under strong acidic conditions – pH 2 – formation of iodosulfuron‐methyl) |
color | Off-White to Pale Beige |
Water Solubility | Solubility in water (g/l at 20 °C) 0.16 (pH 5) 25.0 (pH 7) 65.0 (pH 9). |
CAS DataBase Reference | 144550-36-7(CAS DataBase Reference) |
EPA Substance Registry System | Iodosulfuron-methyl-sodium (144550-36-7) |
Safety information for Iodosulfuron methyl sodium
Signal word | Warning |
Pictogram(s) |
Environment GHS09 |
GHS Hazard Statements |
H410:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. P391:Collect spillage. Hazardous to the aquatic environment P501:Dispose of contents/container to..… |
Computed Descriptors for Iodosulfuron methyl sodium
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile Diclofenac Potassium Ornidazole IP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Aceclofenac IP/BP/EP Nimesulide BP SODIUM AAS SOLUTION ZINC AAS SOLUTION BUFFER SOLUTION PH 10.0(BORATE) GOOCH CRUCIBLE SINTERED AQUANIL 5 BERYLLIUM AAS SOLUTION Methylcobalamin (vitamin B12) SODIUM METHYL PARABEN SODIUM VALPROATE Racecadotril XANTHAN GUMRelated products of tetrahydrofuran
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