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HomeProduct name listHexafluoropropylene

Hexafluoropropylene

Synonym(s):Hexafluoropropylene;Perfluoropropene

  • CAS NO.:116-15-4
  • Empirical Formula: C3F6
  • Molecular Weight: 150.02
  • MDL number: MFCD00000447
  • EINECS: 204-127-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-12-18 14:08:52
Hexafluoropropylene Structural

What is Hexafluoropropylene?

Chemical properties

Hexafluoropropylene (HFP) is a colourless, odourless, non-flammable gas that is only slightly soluble in water. It is used as chemical intermediate primarily in the synthesis of fluoropolymers, fluoro-elastomers and fluorinated materials (e.g. perfluoropolyether functional fluids, oils and greases).

The Uses of Hexafluoropropylene

Hexafluoropropene is used in the synthesis of polyvinylidene fluoride-co-hexafluoropropylene, a polymer which is currently being used in various fields of the nano and electronic sector ranging from membranes to nanoparticles.

Preparation

Hexafluoropropylene can be produced by pyrolysis of tetrafluoroethylene (TFE):
3 CF2=CF2 → 2 CF3CF=CF
This reaction is carried out in a closed continuous reactor at 600 to 900°C. The yield can be improved at low partial pressure, achieved either by operating under reduced total pressure (down to 0.1 bar) or by injecting an inert diluent such as steam or CO2.
Significant quantities of by-products, including the highly toxic perfluoroisobutylene (PFIB), are formed during the pyrolysis of TFE. Such by-products are either incinerated directly or are collected and transported for incineration at a remote facility.
Hexafluoropropylene can also be prepared from chlorodifluoromethane, or produced from various chlorofluorocarbons.

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 4054, 1951 DOI: 10.1021/ja01152a548

General Description

Hexafluoropropylene is an odorless, colorless gas. Hexafluoropropylene is noncombustible. Hexafluoropropylene can asphyxiate by the displacement of air. Exposure of the container to prolonged heat or fire can cause Hexafluoropropylene to rupture violently and rocket.

Reactivity Profile

Halogenated aliphatic compounds, such as Hexafluoropropylene, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. Above a minimum oxygen pressure, the reaction of oxygen difluoride and hexafluoropropene to yield the Hexafluoropropylene oxide becomes explosive, Chem. Abs., 1987, 107, 175302. The reaction of hexafluoropropene with grignard reagent (subst. phenylmagnesium bromides) led to explosion, Fluorine Chem., 1981, 18, 25.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.

Fire Hazard

Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.

Flammability and Explosibility

Non flammable

Properties of Hexafluoropropylene

Melting point: −153 °C(lit.)
Boiling point: −28 °C(lit.)
Density  1,583 g/cm3
vapor pressure  587.952kPa at 25℃
refractive index  1.4000
form  gas
Water Solubility  82mg/L at 28℃
BRN  1705671
Stability: Stable. Incompatible with alkali metals, powdered metals.
CAS DataBase Reference 116-15-4(CAS DataBase Reference)
NIST Chemistry Reference Propene, hexafluoro-(116-15-4)
EPA Substance Registry System Hexafluoropropene (116-15-4)

Safety information for Hexafluoropropylene

Signal word Warning
Pictogram(s)
ghs
Gas Cylinder
Compressed Gases
GHS04
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H280:Gases under pressure
H332:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H371:Specific target organ toxicity, single exposure
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P410+P403:Protect from sunlight. Store in a well-ventilated place.

Computed Descriptors for Hexafluoropropylene

InChIKey HCDGVLDPFQMKDK-UHFFFAOYSA-N

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