hexafluorophosphate
- CAS NO.:870987-63-6
- Empirical Formula: C42H34F10IrN4.PF6
- Molecular Weight: 1121.91
- MDL number: MFCD27952556
- Update Date: 2023-05-11 17:26:00
What is hexafluorophosphate?
The Uses of hexafluorophosphate
[4,?4''-?Bis(tert-butyl)?-?2,?2''-?bipyridine]?bis[3,?5-?difluoro-?2-?[5-?(trifluoromethyl)?-?2-?pyridinyl]?phenyl]?iridium(III) hexafluorophosphate is commonly used as a catalyst in the synthesis of various compounds such as saturated N-?heterocycles from aldehydes, fosmidomycin analogue, and many more.
The Uses of hexafluorophosphate
(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.
Properties of hexafluorophosphate
Melting point: | >300 °C |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
solubility | Chloroform (Slightly) |
form | crystal |
color | yellow |
CAS DataBase Reference | 870987-63-6 |
Safety information for hexafluorophosphate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for hexafluorophosphate
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Ir[p-F(Me)ppy]2(dtbbpy)PF6
Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-)
Ir[dFppy]2(dtbbpy)PF6
Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate
[Ir(dtbbpy)(ppy)2][PF6]
[Ir{dFCF3ppy}2(bpy)]PF6
Ir[p-F(t-Bu)-ppy]3
(2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate
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