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Home Product name list[Ir(dtbbpy)(ppy)2][PF6]

[Ir(dtbbpy)(ppy)2][PF6]

Synonym(s):[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate;[Ir(dtbbpy)(ppy)₂][PF₆];Ir Photocatalyst

CAS NO.：676525-77-2
Empirical Formula: C40H40F6IrN4P
Molecular Weight: 913.97
MDL number: MFCD28369259
SAFETY DATA SHEET (SDS)
Update Date: 2023-06-08 17:06:35

[Ir(dtbbpy)(ppy)2][PF6] Structural

What is [Ir(dtbbpy)(ppy)2][PF6]?

The Uses of [Ir(dtbbpy)(ppy)2][PF6]

[Ir(dtbbpy)(ppy)₂]PF₆ is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
Aryl-alkyl C?C reductive cross-coupling reactions.

Properties of [Ir(dtbbpy)(ppy)2][PF6]

storage temp.	2-8°C
form	crystal
color	yellow
λmax	380nm(CH2Cl2)(lit.)

Safety information for [Ir(dtbbpy)(ppy)2][PF6]

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation
Precautionary Statement Codes	P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection.

Computed Descriptors for [Ir(dtbbpy)(ppy)2][PF6]

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