[Ir(dtbbpy)(ppy)2][PF6]
Synonym(s):[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate;[Ir(dtbbpy)(ppy)2][PF6];Ir Photocatalyst
- CAS NO.:676525-77-2
- Empirical Formula: C40H40F6IrN4P
- Molecular Weight: 913.97
- MDL number: MFCD28369259
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:35
What is [Ir(dtbbpy)(ppy)2][PF6]?
The Uses of [Ir(dtbbpy)(ppy)2][PF6]
[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:
- Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
- Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
- Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
- Aryl-alkyl C?C reductive cross-coupling reactions.
Properties of [Ir(dtbbpy)(ppy)2][PF6]
storage temp. | 2-8°C |
form | crystal |
color | yellow |
λmax | 380nm(CH2Cl2)(lit.) |
Safety information for [Ir(dtbbpy)(ppy)2][PF6]
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for [Ir(dtbbpy)(ppy)2][PF6]
New Products
Tubulysin D Tubulysin I Tubulysin G Tubulysin H 4,4-DIFLUOROCYCLOHEXANAMINE 4-(Benzyloxy)-3-bromophenylacetic Acid 1,2,3,6-TETRAHYDROPYRIDINE HYDROCHLORIDE CYCLOBUTYLAMINE HYDROCHLORIDE 2,2-Difluoropropanol 3-Aminocyclobutanone hydrochloride 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol (1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine Imeglimin Hydrochloride IH 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate Fuel shell Lubiprostone Latanoprostene Bunod Magnesium Trisilicate Flame Retardant Zinc Borate (R)-(3-(3-fluoro-4- thiomorpholinophenyl)-2- oxooxazolidin-4-yl) methyl methanesulfonate methyl 3-fluoro-4- thiomorpholino phenylcarbamate 1H-Imidazole-4-carbonitrile 7-Methoxyquinoline-4-carboxylic acidRelated products of tetrahydrofuran
Rhodamine B
COUMARIN 7
Coumarin 6
N,N'- Dibutylquinacridone
Bis[2-(2-benzothiazoly)phenolato]zinc(II)
Tris(2-phenylpyridine)iridium (Ir(ppy)3)
2,6-bis(diphenylaMino)anthracene-9,10-dione
(2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate
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