HEPTENOPHOS
Synonym(s):7-Chlorobicyclo[3.2.0]hepta-2,6-dien-6-yl dimethyl phosphate
- CAS NO.:23560-59-0
- Empirical Formula: C9H12ClO4P
- Molecular Weight: 250.62
- MDL number: MFCD00055303
- EINECS: 245-737-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is HEPTENOPHOS?
Description
Heptenophos is a light brown liquid or crystalline mass. It is soluble in water (2.2 g/L at 20 ?C) and miscible with most organic solvents, except aliphatic hydrocarbons. Log Kow = 2.32. Heptenophos is hydrolyzed in acidic and alkaline media.
Chemical properties
Pale amber liquid; miscible in most organic solvents; soluble in xylene, acetone, and methanol.
The Uses of HEPTENOPHOS
Heptenophos is used to control sucking pests (primarily aphids) in a wide range of crops. It is also used as an ectoparasiticide to control ticks, lice, mites and fleas in farm animals and pets.
The Uses of HEPTENOPHOS
Insecticide.
The Uses of HEPTENOPHOS
Heptenophos is a pesticide used for fruits and vegetables.
Definition
A nonpersistent contact and systematic phosphate insecticide.
Hazard
Poison; moderately toxic.
Metabolic pathway
Metabolism of heptenophos in soils is by hydrolysis to 7-chloro-bicyclo[3.2.0]hept-2-en-6-one, further transformations of which involve microbially-mediated Baeyer-Villiger oxidations of the cyclobutanone moiety, ring opening of the resultant lactones, dechlorination and dehydrochlorination followed by ultimate mineralisation to CO2 and conversion to unextractable soil-bound residues. In rats, 7-chlorobicyclo[3.2.0]hept-2-en-6-one is further transformed to give the Favorskiirearranged product bicyclo[3.l.0]hex-2-en-6-exo-carboxylic acid as a urinary metabolite.
Metabolism
In rats 90% of heptenophos is excreted in the urine and 6% in the feces as water-soluble metabolites within 6 days after oral administration. In plant (lettuce), it is completely transformed to watersoluble metabolites without accumulation within 4 d. In soil, it is rapidly degraded bymicroorganisms, DT50 (20 ?C) being less than 4 h.
Degradation
Heptenophos is hydrolysed in acidic and alkaline media (PM).
Toxicity evaluation
Acute oral LD50 for rats is 96–121 mg/kg. Inhalation LC50 (4 h) for rats is 0.95 mg/L air. NOEL (2 yr) for rats is 15 mg/kg diet (0.75 mg/kg/d). ADI is 3 μg/kg b.w.
Properties of HEPTENOPHOS
Melting point: | 25°C |
Boiling point: | bp0.001 94-95° |
Density | d420 1.294 |
vapor pressure | 6.5 x 10-2 Pa (15 °C) |
Flash point: | 2 °C |
storage temp. | APPROX 4°C
|
form | liquid |
Water Solubility | 2200 mg l-1 (20 °C) |
EPA Substance Registry System | Heptenophos (23560-59-0) |
Safety information for HEPTENOPHOS
Signal word | Danger |
Pictogram(s) |
Skull and Crossbones Acute Toxicity GHS06 Environment GHS09 |
GHS Hazard Statements |
H301:Acute toxicity,oral H312:Acute toxicity,dermal H330:Acute toxicity,inhalation H410:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for HEPTENOPHOS
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