Hendecanoic acid
Synonym(s):1-Decanecarboxylic acid;Hendecanoic acid;Undecanoic acid
- CAS NO.:112-37-8
- Empirical Formula: C11H22O2
- Molecular Weight: 186.29
- MDL number: MFCD00002730
- EINECS: 203-964-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-19 20:33:22
What is Hendecanoic acid?
Description
Undecanoic acid is a saturated fatty acid containing eleven carbons (C11:0). It is cytotoxic to certain filamentous fungi and is used to study fungal mechanisms of resistance. Undecanoic acid is also used to acylate larger molecules.
Chemical properties
white to pale yellowish low melting solid
Chemical properties
Undecanoic acid has a faint fatty, aldehydic odor.
Occurrence
Occurs naturally in butter and in the oil of Artemisisa frigida Willd.; also reported found in the oils of Chamaecyparis pisifera Engl., wild thyme, Thymus marschollianus and coconut. Also reported found in apple, banana, sour cherry, lemon and mandarin peel oil, grapefruit juice, guava, grapes, papaya, many cheeses, milk powder, chicken and beef fat, cooked mutton, cured pork, beer, cognac, rum, whiskies, white wine, tea, coconut milk, beans, licorice, mango, mushrooms, rice, sake, wort, loquat, scallop and maté.
The Uses of Hendecanoic acid
Intermediates of Liquid Crystals
The Uses of Hendecanoic acid
Undecanoic Acid is a saturated fatty acid. It may be used to activate orphan G protein-coupled receptor GPR40.
The Uses of Hendecanoic acid
Undecanoic acid was used in the formation of cycloamylose crystals.
Definition
ChEBI: A straight-chain, eleven-carbon saturated medium-chain fatty acid found in body fluids; the most fungitoxic of the C7:0 - C18:0 fatty acid series.
Preparation
Hendecanoic acid can be produced by reduction of Undecylenic acid, which is generally obtained from Castor oil.
Aroma threshold values
Detection: 10 ppb
Taste threshold values
Taste characteristics at 20 ppm: waxy, creamy, cheese-like with a fatty dairy mouthfeel.
Synthesis Reference(s)
Tetrahedron Letters, 30, p. 5293, 1989 DOI: 10.1016/S0040-4039(01)93768-2
General Description
White crystalline solid. Insoluble in water. Specific gravity 0.85. Hence floats on water.
Air & Water Reactions
Dust explosion is possible. [USCG, 1999]. Insoluble in water.
Reactivity Profile
A weak carboxylic acid. Neutralizes bases with the evolution of substantial amounts of heat to produce water plus a salt. Reacts with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Can generate flammable and/or toxic gases and heat by reaction with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Reacts in with aqueous solutions of nitrites and thiosulfates (to give H2S and SO3) and dithionites (to give SO2) and heat. Reaction with solutions of carbonates and bicarbonates generate a harmless gas (carbon dioxide) but still heat. Can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. May initiate polymerization reactions. May serve as a catalyst.
Health Hazard
May be harmful by inhalation, ingestion or skin absorption. Material is irritating to mucous membrane and upper respiratory tract. Causes eye and skin irritation.
Fire Hazard
Special Hazards of Combustion Products: Dust explosion is possible.
Properties of Hendecanoic acid
Melting point: | 28-31 °C(lit.) |
Boiling point: | 228 °C160 mm Hg(lit.) |
Density | 0.89 g/cm3 (20℃) |
refractive index | 1.4202 |
FEMA | 3245 | UNDECANOIC ACID |
Flash point: | >230 °F |
storage temp. | room temp |
solubility | 0.05g/l insoluble |
form | Low Melting Solid |
pka | 4.79±0.10(Predicted) |
color | White to pale yellow |
Specific Gravity | 0.9948 |
Odor | at 100.00 %. waxy creamy cheese fatty coconut |
explosive limit | 0.6%(V) |
Water Solubility | insoluble |
JECFA Number | 108 |
BRN | 1759287 |
CAS DataBase Reference | 112-37-8(CAS DataBase Reference) |
NIST Chemistry Reference | Undecanoic acid(112-37-8) |
EPA Substance Registry System | Undecanoic acid (112-37-8) |
Safety information for Hendecanoic acid
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for Hendecanoic acid
InChIKey | ZDPHROOEEOARMN-UHFFFAOYSA-N |
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