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HomeProduct name listGITOXIGENIN

GITOXIGENIN

  • CAS NO.:545-26-6
  • Empirical Formula: C23H34O5
  • Molecular Weight: 390.51
  • MDL number: MFCD00021174
  • EINECS: 208-886-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-05-04 17:34:39
GITOXIGENIN Structural

What is GITOXIGENIN?

Chemical properties

light yellow flakes

The Uses of GITOXIGENIN

Gitoxigenin is a related compound of Digitoxigenin, which has been used in a study to assess its stereochemical effects in cancer cytotoxicity. Digitoxigenin has also been used in a study to investigate the advantage of gold(I)-catalyzed glycosidation of glycosyl o-alkyl benzoates to assemble digitoxin.

What are the applications of Application

Gitoxigenin is a 16β-substituted digitoxigenin

Definition

ChEBI: Gitoxigenin is a 3beta-hydroxy steroid, a 14beta-hydroxy steroid and a 16beta-hydroxy steroid. It derives from a hydride of a 5beta-cardanolide.

Biochem/physiol Actions

Structure-activity relationships for 16β-substituted digitoxigenins as inhibitors of Na+/K+ ATPases.

Purification Methods

Recrystallisation of gitoxigenin from aqueous EtOH produces plates of the sesquihydrate which dehydrate on drying at 100o in vacuo. It also recrystallises from Me2CO/MeOH and from EtOAc (the crystals contain 1 mol of EtOAc) with [] D +24.8o (c 1, dioxane). It has UV with max at 310, 485 and 520nm in 96% H2SO4. On heating with ethanolic HCl it yields digitaligenin with loss of H2O. [Smith J Chem Soc 23 1931, Beilstein 8 IV 2456.]

Properties of GITOXIGENIN

Melting point: ~230 °C
Boiling point: 435.71°C (rough estimate)
Density  1.0639 (rough estimate)
refractive index  1.6120 (estimate)
storage temp.  −20°C
pka 14.56±0.70(Predicted)
Merck  13,4445

Safety information for GITOXIGENIN

Computed Descriptors for GITOXIGENIN

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