Geranylacetone
- CAS NO.:3796-70-1
- Empirical Formula: C13H22O
- Molecular Weight: 194.31
- MDL number: MFCD00008910
- EINECS: 223-269-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-25 23:13:37
What is Geranylacetone?
Chemical properties
6,10-Dimethyl-5,9-undecadien-2-one has a green and rosy floral odor and fresh-floral, light, but rather penetrating sweet-rosy, slightly green, magnolia-like odor. It blends well in lavender and fruity notes, where it imparts a clean and natural character. It helps to round out floral bouquets
Occurrence
Reported found in oil of citronella, yellow passion fruit, peppermint, Scotch spearmint oil, Japanese seafood, scallop, tomato, tomato paste, citrus peel oils, carrots, papaya, melon, Parmesan cheese, milk powder, cognac, tea, starfruit, figs, mango, red sage, nectarines, clams, pork, anise, and hyssop
The Uses of Geranylacetone
(E)-6,10-Dimethylundeca-5,9-dien-2-one is diastereoselective used in preparation of Geranyl Acetone by Carroll reaction of linalool with Acetoacetate.
What are the applications of Application
Geranylacetone is a racemic geranylacetone mixture
Definition
ChEBI: A monoterpene ketone in which an (E)-geranyl group is bonded to one of the alpha-methyls of acetone. It is a component of essential oils from various plants including Nelumbo nucifera.
Preparation
By reaction of linalool and ethyl acetoacetate with an alkaline catalyst and subsequent rearrangement and decarboxylation.
Aroma threshold values
Detection: 60 ppb to 6.4 ppm
Taste threshold values
Taste characteristics at 12 ppm: floral, fruity, fatty, green, pear, apple and banana nuances
Properties of Geranylacetone
Boiling point: | 254-258 °C(lit.) |
Density | 0.873 g/mL at 25 °C(lit.) |
refractive index | n |
FEMA | 3542 | 6,10-DIMETHYL-5,9-UNDECADIEN-2-ONE |
Flash point: | >230 °F |
solubility | Very slightly soluble in water, soluble in alcohol and oils, 10% soluble in propylene glycol. |
form | oily liquid |
color | pale yellowish or almoti colorless |
Specific Gravity | 0.873 |
Odor | at 100.00 %. fresh green fruity waxy rose woody magnolia tropical |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
JECFA Number | 1122 |
BRN | 1722277 |
CAS DataBase Reference | 3796-70-1(CAS DataBase Reference) |
NIST Chemistry Reference | 5,9-Undecadien-2-one, 6,10-dimethyl-, (E)-(3796-70-1) |
EPA Substance Registry System | 5,9-Undecadien-2-one, 6,10-dimethyl-, (5E)- (3796-70-1) |
Safety information for Geranylacetone
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Geranylacetone
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