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HomeProduct name listGeranylacetone

Geranylacetone

  • CAS NO.:3796-70-1
  • Empirical Formula: C13H22O
  • Molecular Weight: 194.31
  • MDL number: MFCD00008910
  • EINECS: 223-269-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-19 15:53:33
Geranylacetone Structural

What is Geranylacetone?

Chemical properties

6,10-Dimethyl-5,9-undecadien-2-one has a green and rosy floral odor and fresh-floral, light, but rather penetrating sweet-rosy, slightly green, magnolia-like odor. It blends well in lavender and fruity notes, where it imparts a clean and natural character. It helps to round out floral bouquets

Occurrence

Reported found in oil of citronella, yellow passion fruit, peppermint, Scotch spearmint oil, Japanese seafood, scallop, tomato, tomato paste, citrus peel oils, carrots, papaya, melon, Parmesan cheese, milk powder, cognac, tea, starfruit, figs, mango, red sage, nectarines, clams, pork, anise, and hyssop

The Uses of Geranylacetone

(E)-6,10-Dimethylundeca-5,9-dien-2-one is diastereoselective used in preparation of Geranyl Acetone by Carroll reaction of linalool with Acetoacetate.

What are the applications of Application

Geranylacetone is a racemic geranylacetone mixture

Definition

ChEBI: A monoterpene ketone in which an (E)-geranyl group is bonded to one of the alpha-methyls of acetone. It is a component of essential oils from various plants including Nelumbo nucifera.

Preparation

By reaction of linalool and ethyl acetoacetate with an alkaline catalyst and subsequent rearrangement and decarboxylation.

Aroma threshold values

Detection: 60 ppb to 6.4 ppm

Taste threshold values

Taste characteristics at 12 ppm: floral, fruity, fatty, green, pear, apple and banana nuances

Properties of Geranylacetone

Boiling point: 254-258 °C(lit.)
Density  0.873 g/mL at 25 °C(lit.)
refractive index  n20/D 1.467(lit.)
FEMA  3542 | 6,10-DIMETHYL-5,9-UNDECADIEN-2-ONE
Flash point: >230 °F
solubility  Very slightly soluble in water, soluble in alcohol and oils, 10% soluble in propylene glycol.
form  oily liquid
color  pale yellowish or almoti colorless
Specific Gravity 0.873
Odor at 100.00 %. fresh green fruity waxy rose woody magnolia tropical
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
JECFA Number 1122
BRN  1722277
CAS DataBase Reference 3796-70-1(CAS DataBase Reference)
NIST Chemistry Reference 5,9-Undecadien-2-one, 6,10-dimethyl-, (E)-(3796-70-1)
EPA Substance Registry System 5,9-Undecadien-2-one, 6,10-dimethyl-, (5E)- (3796-70-1)

Safety information for Geranylacetone

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Geranylacetone

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