Fullerene C60
- CAS NO.:99685-96-8
- Empirical Formula: C60
- Molecular Weight: 720.64
- MDL number: MFCD00151408
- EINECS: 205-105-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-01 18:09:03
What is Fullerene C60?
Description
Fullerene C60 is a molecule with prominent electron acceptor property composed of 60 carbons in the shape of a hollow football with 20 hexagons and 12 pentagons. Fullerene is unsaturated, each carbon connecting to 3 other carbons instead of 4 with fused 5 and 6 membered rings.
Description
The architect Buckminster Fuller popularized geodesic domes in the late 1940s. The domes are structures that sustain their own weight and, despite their curved appearance, consist of planar equilateral triangles.
When chemists Harold W. Kroto at the University of Sussex (Falmer, UK); Robert F. Curl, Jr., and Richard E. Smalley at Rice University (Houston); and co-workers discovered the spherical C60 molecule in 1985, it was natural to name it buckminsterfullerene or, colloquially, “buckyballs”. Although Fuller’s domes consist only of triangles, C60 contains regular pentagons and hexagons.
The same researchers, who went on to win the 1996 Nobel Prize in Chemistry, synthesized other nonspherical fullerenes such as C70. Fullerenes also exist in nature, primarily in soot; but they have also been observed in outer space.
Buckminsterfullerene, like other carbon allotropes, is black. But, unlike other carbons, it is soluble in nonoxygenated organic solvents such as toluene and carbon disulfide. The solutions are purple, magenta, or green, depending on the concentration and solvent–solute interactions.
Many C60 derivatives have been prepared, some with functional groups that can participate in subsequent reactions or catalysis. Fullerenes also have applications in nanotechnology.
Buckminsterfullerene, of course, is noteworthy for its similarity to a soccer ball. So keep it in mind when you watch this year’s men’s FIFA World Cup competition, which begins on June 14.
Chemical properties
black to brown crystalline powder
The Uses of Fullerene C60
Fullerene C60 powder is useful for biomedical applications such as the design of high-performance MRI contrast agents, x-ray imaging contrast agents and photodynamic therapy. It is also essential for single-walled carbon nanotubes with narrow diameter-distribution. It is used as light-activated antimicrobial agent. It also finds application in the field of nanotechnology, heat resistance and superconductivity.
Definition
ChEBI: Fullerene C60 is a fullerene. It has a role as a geroprotector. It is a polyhedral CARBON structure composed of around 60-80 carbon atoms in pentagon and hexagon configuration. They are named after Buckminster Fuller because of structural resemblance to geodesic domes. Fullerenes can be made in high temperature such as arc discharge in an inert atmosphere.
General Description
This product has been enhanced for energy efficiency.
Properties of Fullerene C60
Melting point: | >280 °C(lit.) |
Boiling point: | 500-600℃ subl. |
Density | 5.568 |
RTECS | LS9252500 |
Flash point: | 94 °C |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | organic solvents: soluble |
form | sublimed |
appearance | shiny black needle-like crystals |
color | Dark brown to black |
Water Solubility | Soluble in toluene. Insoluble in water. |
Merck | 14,1462 |
BRN | 5901022 |
Stability: | Stable. Highly flammable. Incompatible with strong oxidizing agents. |
EPA Substance Registry System | [5,6]Fullerene-C60-Ih (99685-96-8) |
Safety information for Fullerene C60
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Fullerene C60
InChIKey | XMWRBQBLMFGWIX-UHFFFAOYSA-N |
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