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HomeProduct name listEthyl 2-trans-4-cis-decadienoate

Ethyl 2-trans-4-cis-decadienoate

  • CAS NO.:3025-30-7
  • Empirical Formula: C12H20O2
  • Molecular Weight: 196.29
  • MDL number: MFCD00082225
  • EINECS: 221-178-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-31 09:08:01
Ethyl 2-trans-4-cis-decadienoate Structural

What is Ethyl 2-trans-4-cis-decadienoate?

Chemical properties

clear colorless to yellowish liquid

Chemical properties

Ethyl (2E,4Z)-2,4-Decadienoate has been identified in pears and has the typical aroma of Williams pears. Synthesis of ethyl (2E,4Z)-2,4-decadienoate starts from (Z)-1-heptenyl bromide, which is converted into a 1-heptenyllithium cuprate complex with lithium and copper iodide. Reaction with ethyl propiolate yields a mixture of 95% ethyl (2E,4Z)- and 5% ethyl (2E,4E)-2,4-decadienoate. Pure ethyl (2E,4Z)-2,4-decadienoate is obtained by fractional distillation. A biotechnological process for its preparation has been developed.

Chemical properties

Ethyl-trans-2, cis-4-decadienoate has a characteristic pear-like flavor and a light fruity aroma.

Occurrence

Reported found in Bartlett pears, apple, grape, durian (Durio zibethinus), pear brandy, quince and spineless monkey orange (Strychnos madagasc).

The Uses of Ethyl 2-trans-4-cis-decadienoate

Potential applications include the profile enhancement of guava, melon, pear, apple, banana, kiwi, grape, golden delicious apple, fruit cocktail juices, fruit nectar, mamey and other tropical backgrounds.

Definition

ChEBI: Ethyl (2E,4Z)-deca-2,4-dienoate is a fatty acid ethyl ester resulting from the formal condensation of the carboxy group of (2E,4E)-deca-2,4-dienoic acid with the hydroxy group of ethanol. It has a role as a plant metabolite, a flavouring agent, a fragrance and a kairomone. It is functionally related to a (2E,4E)-deca-2,4-dienoic acid.

Aroma threshold values

Detection: 100 ppb. Aroma characteristics at 1.0%: sweet ripe pear, creamy and slightly fatty with fruity, green, waxy apple, fleshy nuances

Taste threshold values

Taste characteristics at 5 ppm: ripe pear, green fruity, waxy apple, tropical notes, fatty golden delicious apple fleshy. Taste characteristics at 20 ppm: green, fruity, apple and pear with waxy tropical nuances.

Synthesis Reference(s)

Tetrahedron, 36, p. 1961, 1980 DOI: 10.1016/0040-4020(80)80209-2

General Description

Natural occurrence: Apple, pear, grape, pear brandy and quince.

Biochem/physiol Actions

Odor at 1.0%

Synthesis

Synthetically via the lithium vinyl cuprates.

Properties of Ethyl 2-trans-4-cis-decadienoate

Melting point: -60 °C
Boiling point: 70-72 °C0.05 mm Hg(lit.)
Density  0.905 g/mL at 25 °C(lit.)
vapor pressure  1.6hPa at 21.1℃
FEMA  3148 | ETHYL TRANS-2,CIS-4-DECADIENOATE
refractive index  n20/D 1.486(lit.)
Flash point: >230 °F
storage temp.  2-8°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  neat
color  Colourless
Odor at 10.00 % in dipropylene glycol. green waxy pear apple sweet fruity tropical
JECFA Number 1192
BRN  1724176
EPA Substance Registry System 2,4-Decadienoic acid, ethyl ester, (2E,4Z)- (3025-30-7)

Safety information for Ethyl 2-trans-4-cis-decadienoate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for Ethyl 2-trans-4-cis-decadienoate

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