Contact us: +91 9550333722 040 - 40102781
Structured search
India
Choose your country
Different countries will display different contents
Try our best to find the right business for you.
My chemicalbook

Welcome back!

HomeProduct name listEthyl 2-trans-4-cis-decadienoate

Ethyl 2-trans-4-cis-decadienoate

  • CAS NO.:3025-30-7
  • Empirical Formula: C12H20O2
  • Molecular Weight: 196.29
  • MDL number: MFCD00082225
  • EINECS: 221-178-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-07-31 09:08:01
Ethyl 2-trans-4-cis-decadienoate Structural

What is Ethyl 2-trans-4-cis-decadienoate?

Chemical properties

clear colorless to yellowish liquid

Chemical properties

Ethyl (2E,4Z)-2,4-Decadienoate has been identified in pears and has the typical aroma of Williams pears. Synthesis of ethyl (2E,4Z)-2,4-decadienoate starts from (Z)-1-heptenyl bromide, which is converted into a 1-heptenyllithium cuprate complex with lithium and copper iodide. Reaction with ethyl propiolate yields a mixture of 95% ethyl (2E,4Z)- and 5% ethyl (2E,4E)-2,4-decadienoate. Pure ethyl (2E,4Z)-2,4-decadienoate is obtained by fractional distillation. A biotechnological process for its preparation has been developed.

Chemical properties

Ethyl-trans-2, cis-4-decadienoate has a characteristic pear-like flavor and a light fruity aroma.

Occurrence

Reported found in Bartlett pears, apple, grape, durian (Durio zibethinus), pear brandy, quince and spineless monkey orange (Strychnos madagasc).

The Uses of Ethyl 2-trans-4-cis-decadienoate

Potential applications include the profile enhancement of guava, melon, pear, apple, banana, kiwi, grape, golden delicious apple, fruit cocktail juices, fruit nectar, mamey and other tropical backgrounds.

Definition

ChEBI: Ethyl (2E,4Z)-deca-2,4-dienoate is a fatty acid ethyl ester resulting from the formal condensation of the carboxy group of (2E,4E)-deca-2,4-dienoic acid with the hydroxy group of ethanol. It has a role as a plant metabolite, a flavouring agent, a fragrance and a kairomone. It is functionally related to a (2E,4E)-deca-2,4-dienoic acid.

Aroma threshold values

Detection: 100 ppb. Aroma characteristics at 1.0%: sweet ripe pear, creamy and slightly fatty with fruity, green, waxy apple, fleshy nuances

Taste threshold values

Taste characteristics at 5 ppm: ripe pear, green fruity, waxy apple, tropical notes, fatty golden delicious apple fleshy. Taste characteristics at 20 ppm: green, fruity, apple and pear with waxy tropical nuances.

Synthesis Reference(s)

Tetrahedron, 36, p. 1961, 1980 DOI: 10.1016/0040-4020(80)80209-2

General Description

Natural occurrence: Apple, pear, grape, pear brandy and quince.

Biochem/physiol Actions

Odor at 1.0%

Synthesis

Synthetically via the lithium vinyl cuprates.

Properties of Ethyl 2-trans-4-cis-decadienoate

Melting point: -60 °C
Boiling point: 70-72 °C0.05 mm Hg(lit.)
Density  0.905 g/mL at 25 °C(lit.)
vapor pressure  1.6hPa at 21.1℃
FEMA  3148 | ETHYL TRANS-2,CIS-4-DECADIENOATE
refractive index  n20/D 1.486(lit.)
Flash point: >230 °F
storage temp.  2-8°C
solubility  Chloroform (Slightly), Methanol (Slightly)
form  neat
color  Colourless
Odor at 10.00 % in dipropylene glycol. green waxy pear apple sweet fruity tropical
JECFA Number 1192
BRN  1724176
EPA Substance Registry System 2,4-Decadienoic acid, ethyl ester, (2E,4Z)- (3025-30-7)

Safety information for Ethyl 2-trans-4-cis-decadienoate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for Ethyl 2-trans-4-cis-decadienoate

Related products of tetrahydrofuran

You may like

  • Ethyl 2,4-Decadienoate CAS 3025-30-7
    Ethyl 2,4-Decadienoate CAS 3025-30-7
    3025-30-7
    View Details
  • Ethyl 2-trans-4-cis-decadienoate CAS 3025-30-7
    Ethyl 2-trans-4-cis-decadienoate CAS 3025-30-7
    3025-30-7
    View Details
  • Ethyl 2-trans-4-cis-decadienoate CAS 3025-30-7
    Ethyl 2-trans-4-cis-decadienoate CAS 3025-30-7
    3025-30-7
    View Details
  • Dimethyl [2-oxo-3-[3-(trifluoromethyl)phenoxy]propyl]phosphonate 99%
    Dimethyl [2-oxo-3-[3-(trifluoromethyl)phenoxy]propyl]phosphonate 99%
    54094-19-8
    View Details
  • 85-81-4 99%
    85-81-4 99%
    85-81-4
    View Details
  • 208111-98-2 (3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-4-[3-(trifluoromethyl)phenoxy]-1-buten- 1-yl]-2H-cyclopenta[b]furan-2-one 99%
    208111-98-2 (3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-4-[3-(trifluoromethyl)phenoxy]-1-buten- 1-yl]-2H-cyclopenta[b]furan-2-one 99%
    208111-98-2
    View Details
  • 2033-24-1 99%
    2033-24-1 99%
    2033-24-1
    View Details
  • Meldrums acid 2033-24-1 99%
    Meldrums acid 2033-24-1 99%
    2033-24-1
    View Details
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.