Ethyl 2-trans-4-cis-decadienoate
- CAS NO.:3025-30-7
- Empirical Formula: C12H20O2
- Molecular Weight: 196.29
- MDL number: MFCD00082225
- EINECS: 221-178-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-07-31 09:08:01
What is Ethyl 2-trans-4-cis-decadienoate?
Chemical properties
clear colorless to yellowish liquid
Chemical properties
Ethyl (2E,4Z)-2,4-Decadienoate has been identified in pears and has the typical aroma of Williams pears. Synthesis of ethyl (2E,4Z)-2,4-decadienoate starts from (Z)-1-heptenyl bromide, which is converted into a 1-heptenyllithium cuprate complex with lithium and copper iodide. Reaction with ethyl propiolate yields a mixture of 95% ethyl (2E,4Z)- and 5% ethyl (2E,4E)-2,4-decadienoate. Pure ethyl (2E,4Z)-2,4-decadienoate is obtained by fractional distillation. A biotechnological process for its preparation has been developed.
Chemical properties
Ethyl-trans-2, cis-4-decadienoate has a characteristic pear-like flavor and a light fruity aroma.
Occurrence
Reported found in Bartlett pears, apple, grape, durian (Durio zibethinus), pear brandy, quince and spineless monkey orange (Strychnos madagasc).
The Uses of Ethyl 2-trans-4-cis-decadienoate
Potential applications include the profile enhancement of guava, melon, pear, apple, banana, kiwi, grape, golden delicious apple, fruit cocktail juices, fruit nectar, mamey and other tropical backgrounds.
Definition
ChEBI: Ethyl (2E,4Z)-deca-2,4-dienoate is a fatty acid ethyl ester resulting from the formal condensation of the carboxy group of (2E,4E)-deca-2,4-dienoic acid with the hydroxy group of ethanol. It has a role as a plant metabolite, a flavouring agent, a fragrance and a kairomone. It is functionally related to a (2E,4E)-deca-2,4-dienoic acid.
Aroma threshold values
Detection: 100 ppb. Aroma characteristics at 1.0%: sweet ripe pear, creamy and slightly fatty with fruity, green, waxy apple, fleshy nuances
Taste threshold values
Taste characteristics at 5 ppm: ripe pear, green fruity, waxy apple, tropical notes, fatty golden delicious apple fleshy. Taste characteristics at 20 ppm: green, fruity, apple and pear with waxy tropical nuances.
Synthesis Reference(s)
Tetrahedron, 36, p. 1961, 1980 DOI: 10.1016/0040-4020(80)80209-2
General Description
Natural occurrence: Apple, pear, grape, pear brandy and quince.
Biochem/physiol Actions
Odor at 1.0%
Synthesis
Synthetically via the lithium vinyl cuprates.
Properties of Ethyl 2-trans-4-cis-decadienoate
Melting point: | -60 °C |
Boiling point: | 70-72 °C0.05 mm Hg(lit.) |
Density | 0.905 g/mL at 25 °C(lit.) |
vapor pressure | 1.6hPa at 21.1℃ |
FEMA | 3148 | ETHYL TRANS-2,CIS-4-DECADIENOATE |
refractive index | n |
Flash point: | >230 °F |
storage temp. | 2-8°C |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | neat |
color | Colourless |
Odor | at 10.00 % in dipropylene glycol. green waxy pear apple sweet fruity tropical |
JECFA Number | 1192 |
BRN | 1724176 |
EPA Substance Registry System | 2,4-Decadienoic acid, ethyl ester, (2E,4Z)- (3025-30-7) |
Safety information for Ethyl 2-trans-4-cis-decadienoate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. P302+P352:IF ON SKIN: wash with plenty of soap and water. |
Computed Descriptors for Ethyl 2-trans-4-cis-decadienoate
Related products of tetrahydrofuran
You may like
-
Ethyl 2,4-Decadienoate CAS 3025-30-7View Details
3025-30-7 -
Ethyl 2-trans-4-cis-decadienoate CAS 3025-30-7View Details
3025-30-7 -
Ethyl 2-trans-4-cis-decadienoate CAS 3025-30-7View Details
3025-30-7 -
77-92-9 99%View Details
77-92-9 -
77-92-9 99%View Details
77-92-9 -
8000-27-9 CEDAR WOOD OIL 99%View Details
8000-27-9 -
AMMONIUM DICHROMATE 7789-09-5 99%View Details
7789-09-5 -
95-54-5 99%View Details
95-54-5