ETHYLDICHLOROPHOSPHINE
- CAS NO.:1498-40-4
- Empirical Formula: C2H5Cl2P
- Molecular Weight: 130.94
- MDL number: MFCD00013617
- EINECS: 216-096-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is ETHYLDICHLOROPHOSPHINE?
Chemical properties
Colorless to light yellow liqui
Synthesis Reference(s)
Canadian Journal of Chemistry, 41, p. 2299, 1963 DOI: 10.1139/v63-333
The Journal of Organic Chemistry, 14, p. 429, 1949 DOI: 10.1021/jo01155a014
General Description
A colorless liquid with a pungent odor. Denser than water. Very toxic by inhalation.
Air & Water Reactions
Highly flammable. Pyrophoric, will spontaneously ignite on contact with water or moisture in air. In water the compound also decomposes to form hydrochloric acid, [AAR 1991].
Reactivity Profile
ETHYL PHOSPHONOUS DICHLORIDE is an acid halide and organophosphate. Flammable/combustible material. May ignite on contact with air or moist air. May burn rapidly with flare-burning effect. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health Hazard
Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire Hazard
Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
Safety Profile
Moderately toxic by inhalation. Corrosive. A severe irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits very toxic fumes of POx, Cl-, and phosphine. See also PHOSPHINE.
Properties of ETHYLDICHLOROPHOSPHINE
Boiling point: | 112 °C(lit.) |
Density | 1.26 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 91 °F |
storage temp. | Flammables area |
form | liquid |
color | colorless |
Sensitive | air sensitive, moisture sensitive |
EPA Substance Registry System | Phosphonous dichloride, ethyl- (1498-40-4) |
Safety information for ETHYLDICHLOROPHOSPHINE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Corrosion Corrosives GHS05 |
GHS Hazard Statements |
H226:Flammable liquids H250:Pyrophoric liquids; Pyrorophoric solids H314:Skin corrosion/irritation |
Precautionary Statement Codes |
P222:Do not allow contact with air. P231:Handle under inert gas. P280:Wear protective gloves/protective clothing/eye protection/face protection. P310:Immediately call a POISON CENTER or doctor/physician. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P422:Store contents under … |
Computed Descriptors for ETHYLDICHLOROPHOSPHINE
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