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HomeProduct name listETHYL DIAZOACETOACETATE

ETHYL DIAZOACETOACETATE

ETHYL DIAZOACETOACETATE Structural

What is ETHYL DIAZOACETOACETATE?

Synthesis Reference(s)

Tetrahedron Letters, 5, p. 2285, 1964 DOI: 10.1002/lipi.19640660210

General Description

Ethyl diazoacetoacetate is a diazo compound. It participates in Rh2(OAc)4-catalyzed reactions with arylalkylamines and diarylamines. Reaction of ethyl diazoacetoacetate with N-methyl pyrrole and pyrrole derivatives has been studied.

Properties of ETHYL DIAZOACETOACETATE

Boiling point: 102-103 °C(Press: 12 Torr)
Density  1.131 g/mL at 25 °C (lit.)
vapor pressure  0.36 psi ( 20 °C)
refractive index  n20/D 1.474(lit.)
Flash point: 185 °F

Safety information for ETHYL DIAZOACETOACETATE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H242:Self-reactive substances and mixtures; and Organic peroxides
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P235:Keep cool.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378:In case of fire: Use … for extinction.
P403+P233:Store in a well-ventilated place. Keep container tightly closed.

Computed Descriptors for ETHYL DIAZOACETOACETATE

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