ETHYL 2-NITROPROPIONATE
- CAS NO.：2531-80-8
- Empirical Formula: C5H9NO4
- Molecular Weight: 147.13
- MDL number: MFCD00024818
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is ETHYL 2-NITROPROPIONATE?
The Uses of ETHYL 2-NITROPROPIONATE
Ethyl 2-nitropropionate is used in the preparation of (-)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst, novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion, 2-ethoxycarbonyl-2-nitropentanal. It is used for enantioselective Michael reactions.
The Uses of ETHYL 2-NITROPROPIONATE
Ethyl 2-nitropropionate was used in the preparation of:
- (?)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst
- novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion
- 2-ethoxycarbonyl-2-nitropentanal
What are the applications of Application
Ethyl 2-nitropropionate is a nitro ester for use in enantioselective Michael reactions
General Description
Ethyl 2-nitropropionate is a nitro ester.
Properties of ETHYL 2-NITROPROPIONATE
| Boiling point: | 75-76 °C/9 mmHg (lit.) |
| Density | 1.13 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 193 °F |
| pka | 5.98±0.10(Predicted) |
| Water Solubility | Not miscible in water. |
| BRN | 774734 |
| EPA Substance Registry System | Propanoic acid, 2-nitro-, ethyl ester (2531-80-8) |
Safety information for ETHYL 2-NITROPROPIONATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for ETHYL 2-NITROPROPIONATE
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