ETHYL 2 3-BUTADIENOATE 95
- CAS NO.：14369-81-4
- Empirical Formula: C6H8O2
- Molecular Weight: 112.13
- MDL number: MFCD01863567
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:37
What is ETHYL 2 3-BUTADIENOATE 95?
The Uses of ETHYL 2 3-BUTADIENOATE 95
Ethyl Buta-2,3-dienoate is a useful reactant for the synthesis of 9H-?pyrrolo[1,?2-?a]?indole derivatives via a phosphine-?promoted Michael addn.?/intramol. Wittig reaction.
The Uses of ETHYL 2 3-BUTADIENOATE 95
Ethyl 2,3-butadienoate may be used in the synthesis of dihydropyrans by reacting with acyclic enones. It may also be used to synthesize spiranic heterocycles by reacting with heterocyclic bis-arylidene ketones via phosphine-catalyzed [3+2] annulations.
General Description
Ethyl 2,3-butadienoate is an α-allenic ester. The reaction of ethyl 2,3-butadienoate with N-tosylated imines in the presence of DABCO (1,4-diazabicyclo[2.2.2]octane) or DMAP (4-dimethylaminopyridine) forms azetidine derivatives or novel dihydropyridine derivatives respectively. The performance of bifunctional N-acyl aminophosphines to catalyze the asymmetric [3+2] cycloaddition of phenylidenemalononitrile with ethyl 2,3-butadienoate has been evaluated.
Properties of ETHYL 2 3-BUTADIENOATE 95
| Boiling point: | 80 °C60 mm Hg(lit.) |
| Density | 0.966 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 116 °F |
| storage temp. | <0°C |
| form | clear liquid |
| color | Colorless to Light yellow |
| λmax | 209nm(MeOH)(lit.) |
Safety information for ETHYL 2 3-BUTADIENOATE 95
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02 |
| GHS Hazard Statements |
H226:Flammable liquids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. |
Computed Descriptors for ETHYL 2 3-BUTADIENOATE 95
New Products
2,2-diethoxyethanethioamide Tubulysin G Tubulysin M 2H-Pyran, 4-ethynyltetrahydro- 2,2-Difluoropropanol 4,4-DIFLUOROCYCLOHEXANAMINE 3-Aminocyclobutanone hydrochloride 4,4-DIFLUOROPIPERIDINE 4-(Benzyloxy)-3-bromophenylacetic Acid (1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine Calcium Sodium Phosphosilicate IH Fuel shell 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile Imeglimin Hydrochloride IH Lubiprostone Latanoprostene Bunod Magnesium Trisilicate Flame Retardant Zinc Borate methyl 3-fluoro-4- thiomorpholino phenylcarbamate (R)-(3-(3-fluoro-4- thiomorpholinophenyl)-2- oxooxazolidin-4-yl) methyl methanesulfonate 1H-Imidazole-4-carbonitrile 7-Methoxyquinoline-4-carbonitrile 7-Methoxyquinoline-4-carboxylic acidRelated products of tetrahydrofuran
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