ETHYL 2-(BROMOMETHYL)ACRYLATE
Synonym(s):2-(Bromomethyl)acrylic acid ethyl ester;Ethyl α-(bromomethyl)acrylate;Ethyl 2-(bromomethyl)-2-propenoate;Ethyl 2-(bromomethyl)propenoate
- CAS NO.：17435-72-2
- Empirical Formula: C6H9BrO2
- Molecular Weight: 193.04
- MDL number: MFCD00031518
- EINECS: 628-033-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is ETHYL 2-(BROMOMETHYL)ACRYLATE?
Chemical properties
Colourless Oil
The Uses of ETHYL 2-(BROMOMETHYL)ACRYLATE
ETHYL 2-(BROMOMETHYL)ACRYLATE is an intermediate used for the synthesis of aza inhibitors of chorismate mutase.
The Uses of ETHYL 2-(BROMOMETHYL)ACRYLATE
It can be employed as an electrophile for various organometallic compounds. The organometallic derivatives of the compound can be used for the synthesis of α-methylene lactones and lactams. It can also be used for the polymerization of functionalized acrylic monomers.
What are the applications of Application
Ethyl Bromomethacrylate is An intermediate in the synthesis of aza inhibitors
General Description
Ethyl 2-(bromomethyl)acrylate is an allylic alkylating reagent.
Purification Methods
If it contains some free acid, add H2O, cool, and neutralise with NaHCO3 until evolution of CO2 ceases. Extract the mixture with Et2O (3x) and dry the combined extracts (Na2SO4, 3hours). Evaporate Et2O and distil the ester collecting fraction b 39-40o/0.9mm and check spectra. [Preparation and NMR: Ramarajan et al. Org Synth Coll Vol VII 211 1990, Beilstein 2 IV 1541.]
Properties of ETHYL 2-(BROMOMETHYL)ACRYLATE
| Melting point: | 134-136℃ |
| Boiling point: | 38 °C/0.8 mmHg (lit.) |
| Density | 1.398 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 178 °F |
| storage temp. | -20°C |
| solubility | Chloroform (Sparingly), Ethyl Acetate (Slightly) |
| form | Liquid |
| color | Colorless to pale yellow |
| BRN | 970108 |
| CAS DataBase Reference | 17435-72-2(CAS DataBase Reference) |
Safety information for ETHYL 2-(BROMOMETHYL)ACRYLATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for ETHYL 2-(BROMOMETHYL)ACRYLATE
| InChIKey | MTCMFVTVXAOHNQ-UHFFFAOYSA-N |
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product: 17435-72-2 Ethyl Bromomethacrylate 98%
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