distrontium diphosphate
Synonym(s):Distrontium diphosphate;Distrontium pyrophosphate;Strontium diphosphate;Strontium metaphosphate oxide
- CAS NO.:13812-81-2
- Empirical Formula: H6O7P2Sr
- Molecular Weight: 267.61
- MDL number: MFCD00799869
- EINECS: 237-461-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is distrontium diphosphate?
Description
Strontium pyrophosphate has the molecular formula of Sr2P2O7 and the molecular weight of 349.1833 g/mol.
Its CAS number is 765305-66-6. It may be prepared by
the solid-state reaction of the dibasic orthophosphate,
or alternately by the precipitation of a soluble Mg salt
with aqueous pyrophosphoric acid:
2SrHPO4 + heat ? Sr2P2O7 +H2O
SrCl2 (aq) +H4P2O7 (aq) ? Sr2P2O7 (solid) + 2HCl (aq)
The solution method produces a hemihydrate,
Sr2P2O7·1/2H2O. This salt decomposes at 575°C to
form β-Sr2P2O7. The transition to the high temperature
form, α-Sr2P2O7 takes place at about 760–780°C.
In the Sr2P2O7 system, the unit-cell parameters of
orthorhombic β-Sr2P2O7 are: a = 8.9839?, b = 13.163 ?,
and c = 5.403 ?. The crystallographic data of Sr2P2O7
are reported to contain two types of sites for Sr2+ ions
in the unit cell.
The Uses of distrontium diphosphate
Strontium pyrophosphate has long been used as a matrix for phosphors used in fluorescent lamps in the lamp industry. These phosphors have strong absorption in the near UV region, which is suitable for excitation of ultraviolet light-emitting diodes (UV-LEDs).
The Uses of distrontium diphosphate
Sr2P2O7 is a promising phosphor host material; showing different emission properties upon doping with rare earth and other elements. Example Eu(2+) doped Sr2P2O7 shows blue emission; Sr2P2O7 doped with Bi(2+) is a red phosphor.
Properties of distrontium diphosphate
Melting point: | >380°C |
form | powder |
EPA Substance Registry System | Diphosphoric acid, strontium salt (1:2) (13812-81-2) |
Safety information for distrontium diphosphate
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for distrontium diphosphate
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