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HomeProduct name listdistrontium diphosphate

distrontium diphosphate

Synonym(s):Distrontium diphosphate;Distrontium pyrophosphate;Strontium diphosphate;Strontium metaphosphate oxide

  • CAS NO.:13812-81-2
  • Empirical Formula: H6O7P2Sr
  • Molecular Weight: 267.61
  • MDL number: MFCD00799869
  • EINECS: 237-461-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-04-23 13:52:06
distrontium diphosphate Structural

What is distrontium diphosphate?

Description

Strontium pyrophosphate has the molecular formula of Sr2P2O7 and the molecular weight of 349.1833 g/mol.
Its CAS number is 765305-66-6. It may be prepared by the solid-state reaction of the dibasic orthophosphate, or alternately by the precipitation of a soluble Mg salt with aqueous pyrophosphoric acid:
2SrHPO4 + heat ? Sr2P2O7 +H2O
SrCl2 (aq) +H4P2O7 (aq) ? Sr2P2O7 (solid) + 2HCl (aq)
The solution method produces a hemihydrate, Sr2P2O7·1/2H2O. This salt decomposes at 575°C to form β-Sr2P2O7. The transition to the high temperature form, α-Sr2P2O7 takes place at about 760–780°C.
In the Sr2P2O7 system, the unit-cell parameters of orthorhombic β-Sr2P2O7 are: a = 8.9839?, b = 13.163 ?, and c = 5.403 ?. The crystallographic data of Sr2P2O7 are reported to contain two types of sites for Sr2+ ions in the unit cell.

The Uses of distrontium diphosphate

Strontium pyrophosphate has long been used as a matrix for phosphors used in fluorescent lamps in the lamp industry. These phosphors have strong absorption in the near UV region, which is suitable for excitation of ultraviolet light-emitting diodes (UV-LEDs).

The Uses of distrontium diphosphate

Sr2P2O7 is a promising phosphor host material; showing different emission properties upon doping with rare earth and other elements. Example Eu(2+) doped Sr2P2O7 shows blue emission; Sr2P2O7 doped with Bi(2+) is a red phosphor.

Properties of distrontium diphosphate

Melting point: >380°C
form  powder
EPA Substance Registry System Diphosphoric acid, strontium salt (1:2) (13812-81-2)

Safety information for distrontium diphosphate

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for distrontium diphosphate

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