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HomeProduct name listDIMETHYLCYANAMIDE

DIMETHYLCYANAMIDE

  • CAS NO.:1467-79-4
  • Empirical Formula: C3H6N2
  • Molecular Weight: 70.09
  • MDL number: MFCD00001767
  • EINECS: 215-991-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-11-28 16:31:44
DIMETHYLCYANAMIDE Structural

What is DIMETHYLCYANAMIDE?

Chemical properties

CLEAR COLORLESS TO YELLOWISH LIQUID

The Uses of DIMETHYLCYANAMIDE

Dimethylcyanamide in the presence of tetrachlorosilane and zinc chloride is used as a promoter for one-pot, three component synthesis of a novel series of 1,3-oxazines. Being a dialkylcyanamide, it has been proved to be a more reactive substrate toward metal-mediated nucleophilic addition than alkylcyanides.

Production Methods

Dimethyl cyanamide is made by the reaction of nitromethane with tris(dimethylamino) arsine.

General Description

Clear liquid.

Air & Water Reactions

Reacts with water to form cyanide gas

Reactivity Profile

Nitriles, such as DIMETHYLCYANAMIDE, may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids. DIMETHYLCYANAMIDE reacts with oxidizers, water, or steam.

Health Hazard

ACUTE/CHRONIC HAZARDS: DIMETHYLCYANAMIDE is an irritant. It reacts with water to produce toxic and flammable vapors.

Fire Hazard

DIMETHYLCYANAMIDE is combustible.

Safety Profile

Poison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by inhalation. Flammable when exposed to heat, flame, or oxidzers. Can react with oxidzing materials. To fight fire, use foam, CO2, or dry chemical. When heated to decomposition or in reaction with water or steam it produces toxic fumes of NOx, and CNand flammable vapors. See also CYANIDE

Properties of DIMETHYLCYANAMIDE

Melting point: -41 °C
Boiling point: 161-163 °C(lit.)
Density  0.867 g/mL at 25 °C(lit.)
refractive index  n20/D 1.41(lit.)
Flash point: 137 °F
storage temp.  Inert atmosphere,2-8°C
solubility  Chloroform (Sparingly), Hexane (Slightly)
form  Liquid
pka -4.76±0.70(Predicted)
color  Clear colorless to yellow
Dielectric constant 37.229999999999997
EPA Substance Registry System Dimethylcyanamide (1467-79-4)

Safety information for DIMETHYLCYANAMIDE

Signal word Danger
Pictogram(s)
ghs
Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H227:Flammable liquids
H301:Acute toxicity,oral
H310:Acute toxicity,dermal
H332:Acute toxicity,inhalation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P262:Do not get in eyes, on skin, or on clothing.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378:In case of fire: Use … for extinction.
P405:Store locked up.
P403+P235:Store in a well-ventilated place. Keep cool.
P501:Dispose of contents/container to..…

Computed Descriptors for DIMETHYLCYANAMIDE

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