Dimethyl trisulfide
- CAS NO.:3658-80-8
- Empirical Formula: C2H6S3
- Molecular Weight: 126.26
- MDL number: MFCD00039808
- EINECS: 222-910-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-11-19 23:02:33
What is Dimethyl trisulfide?
Chemical properties
clear yellow liquid
Chemical properties
Dimethyl trisulfide has a powerful, diffusive, penetrating odor reminiscent of fresh onion
Occurrence
Reported as occurring in the volatile portion of fresh onion juice; the major aroma component in cooked vegetables of the Brassica genus. Also reported found in kohlrabi, cabbage, onion, garlic, shallots, leek, peas, mustard, tomato, wheaten bread, cheeses, milk, cooked chicken, pork, beef, hop oil, beer, brandies, whiskey, sherry, grape wine, cocoa, coffee, roasted peanuts, mushrooms, broccoli, cauliflower, brussels sprouts, radishes, pumpkin, sweet corn, asparagus, black tea, shellfish and squid.
The Uses of Dimethyl trisulfide
Dimethyl trisulfide is reported as a major aroma component in cooked Brassicaceous vegetables. Trap baits containing dimethyl trisulfide have been used to capture Calliphora loewi and other blowflies. Dimethyl trisulfide along with dimethyl sulfide and dimethyl disulfide have been confirmed as volatile compounds given off by the fly-attracting plant known as dead-horse arum (Helicodiceros muscivorus). These flies are attracted to the odor of fetid meat and help pollinate this plant.
Preparation
It is produced by the microorganism, L. cremoris S2.
Definition
ChEBI: Dimethyl trisulfide is an organic trisulfide.
Taste threshold values
Taste characteristics at 2.0 ppm: sulfureous, alliaceous, gassy, savory and meaty with a fresh, vegetative nuance
Synthesis Reference(s)
Tetrahedron Letters, 30, p. 2995, 1989 DOI: 10.1016/S0040-4039(00)99178-0
Properties of Dimethyl trisulfide
Melting point: | −68 °C(lit.) |
Boiling point: | 58 °C15 mm Hg(lit.) |
Density | 1.202 g/mL at 25 °C(lit.) |
refractive index | n |
FEMA | 3275 | DIMETHYL TRISULFIDE |
Flash point: | 133 °F |
storage temp. | Store at -20°C |
solubility | Chloroform (Sparingly), Methanol (Slightly) |
form | Liquid |
color | Clear yellow |
Odor | at 0.10 % in propylene glycol. sulfurous cooked onion savory meaty |
Water Solubility | Insoluble in water. |
JECFA Number | 582 |
BRN | 1731604 |
CAS DataBase Reference | 3658-80-8(CAS DataBase Reference) |
NIST Chemistry Reference | Trisulfide, dimethyl(3658-80-8) |
EPA Substance Registry System | Trisulfide, dimethyl (3658-80-8) |
Safety information for Dimethyl trisulfide
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Dimethyl trisulfide
New Products
4-AMINO-TETRAHYDRO-PYRAN-4-CARBOXYLIC ACID HCL 4-(Dimethylamino)tetrahydro-2H-pyran-4-carbonitrile 4-Aminotetrahydropyran-4-carbonitrile Hydrochloride (R)-3-Aminobutanenitrile Hydrochloride 3-((Dimethylamino)methyl)-5-methylhexan-2-one oxalate 1,4-Dioxa-8-azaspiro[4.5]decane 5-Bromo-2-nitropyridine Nimesulide BP Aceclofenac IP/BP/EP Diclofenac Sodium IP/BP/EP/USP Mefenamic Acid IP/BP/EP/USP Ornidazole IP Diclofenac Potassium THOMAIND PAPER PH 2.0 TO 4.5 1 BOX BUFFER CAPSULE PH 9.2 - 10 CAP SODIUM CHLORIDE 0.1N CVS ALLOXAN MONOHYDRATE 98% PLATINUM 0.5% ON 3 MM ALUMINA PELLETS (TYPE 73) LITHIUM AAS SOLUTION 2-Bromo-1-(bromomethyl)-3-chloro-5-nitrobenzene 2-Bromo-3-nitroaniline N-(3-Hydroxypropyl)-N-methylacetamide 3-Bromo-6-chloropyridazine 4-ethyl-3-nitrobenzoic acidRelated products of tetrahydrofuran
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