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HomeProduct name listDimethyl trisulfide

Dimethyl trisulfide

  • CAS NO.:3658-80-8
  • Empirical Formula: C2H6S3
  • Molecular Weight: 126.26
  • MDL number: MFCD00039808
  • EINECS: 222-910-9
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-11-12 15:22:20
Dimethyl trisulfide Structural

What is Dimethyl trisulfide?

Chemical properties

clear yellow liquid

Chemical properties

Dimethyl trisulfide has a powerful, diffusive, penetrating odor reminiscent of fresh onion

Occurrence

Reported as occurring in the volatile portion of fresh onion juice; the major aroma component in cooked vegetables of the Brassica genus. Also reported found in kohlrabi, cabbage, onion, garlic, shallots, leek, peas, mustard, tomato, wheaten bread, cheeses, milk, cooked chicken, pork, beef, hop oil, beer, brandies, whiskey, sherry, grape wine, cocoa, coffee, roasted peanuts, mushrooms, broccoli, cauliflower, brussels sprouts, radishes, pumpkin, sweet corn, asparagus, black tea, shellfish and squid.

The Uses of Dimethyl trisulfide

Dimethyl trisulfide is reported as a major aroma component in cooked Brassicaceous vegetables. Trap baits containing dimethyl trisulfide have been used to capture Calliphora loewi and other blowflies. Dimethyl trisulfide along with dimethyl sulfide and dimethyl disulfide have been confirmed as volatile compounds given off by the fly-attracting plant known as dead-horse arum (Helicodiceros muscivorus). These flies are attracted to the odor of fetid meat and help pollinate this plant.

Preparation

It is produced by the microorganism, L. cremoris S2.

Definition

ChEBI: Dimethyl trisulfide is an organic trisulfide.

Taste threshold values

Taste characteristics at 2.0 ppm: sulfureous, alliaceous, gassy, savory and meaty with a fresh, vegetative nuance

Synthesis Reference(s)

Tetrahedron Letters, 30, p. 2995, 1989 DOI: 10.1016/S0040-4039(00)99178-0

Properties of Dimethyl trisulfide

Melting point: −68 °C(lit.)
Boiling point: 58 °C15 mm Hg(lit.)
Density  1.202 g/mL at 25 °C(lit.)
refractive index  n20/D 1.602(lit.)
FEMA  3275 | DIMETHYL TRISULFIDE
Flash point: 133 °F
storage temp.  Store at -20°C
solubility  Chloroform (Sparingly), Methanol (Slightly)
form  Liquid
color  Clear yellow
Odor at 0.10 % in propylene glycol. sulfurous cooked onion savory meaty
Water Solubility  Insoluble in water.
JECFA Number 582
BRN  1731604
CAS DataBase Reference 3658-80-8(CAS DataBase Reference)
NIST Chemistry Reference Trisulfide, dimethyl(3658-80-8)
EPA Substance Registry System Trisulfide, dimethyl (3658-80-8)

Safety information for Dimethyl trisulfide

Signal word Warning
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Dimethyl trisulfide

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