dilithium acetylide
- CAS NO.:1070-75-3
- Empirical Formula: C2Li2
- Molecular Weight: 37.9034
- EINECS: 213-980-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-10-17 17:11:56
What is dilithium acetylide?
Chemical properties
crystal(s) white powder(s); decomposes in water, evolves acetylene when dissolved in acid [HAW93]
Preparation
Lithium carbide, Li2C2, may be prepared by the direct combination of lithium and carbon at about 1000°C or by the reaction of lithium metal with acetylene in liquid ammonia. The latter process first yields lithium acetylide, LiC=CH, which decomposes to lithium carbide. The conversion to the carbide is incomplete, however . A convenient laboratory preparation of lithium carbide may be carried out by bubbling acetylene into a solution of n-butyllithium in hexane. The precipitated carbide may be filtered from the reaction mixture, washed, and dried. Lithium carbide is ionic and yields acetylene on hydrolysis.
Properties of dilithium acetylide
Density | 1.650 |
solubility | reacts with H2O; insoluble in organic solvents |
color | white hygroscopic crystals, crystalline |
Safety information for dilithium acetylide
Computed Descriptors for dilithium acetylide
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barium acetylide
SODIUM ACETYLIDE
Lithium acetylide ethylenediamine complex
Silver acetylide
DI-SODIUM ACETYLIDE
copper acetylide
rubidium acetylide
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