DIETHYL DIALLYLMALONATE
- CAS NO.：3195-24-2
- Empirical Formula: C13H20O4
- Molecular Weight: 240.3
- MDL number: MFCD00009126
- EINECS: 221-696-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-04 17:34:37
What is DIETHYL DIALLYLMALONATE?
The Uses of DIETHYL DIALLYLMALONATE
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Definition
ChEBI: Diethyl diallylmalonate is a fatty acid ester.
General Description
Low catalyst loading in ring-closing metathesis reaction of diethyl diallylmalonate has been reported. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.
Properties of DIETHYL DIALLYLMALONATE
| Boiling point: | 128-130 °C/12 mmHg (lit.) |
| Density | 0.994 g/mL at 25 °C (lit.) |
| vapor pressure | 4.266Pa at 25℃ |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | Chloroform, DMSO, Methanol |
| form | Oil |
| color | Clear Colourless |
| Water Solubility | Sparingly Soluble in water. (0.72 g/L) (25°C) |
| BRN | 1790529 |
| CAS DataBase Reference | 3195-24-2(CAS DataBase Reference) |
Safety information for DIETHYL DIALLYLMALONATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for DIETHYL DIALLYLMALONATE
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