DIETHYL DIALLYLMALONATE

CAS NO.：3195-24-2
Empirical Formula: C13H20O4
Molecular Weight: 240.3
MDL number: MFCD00009126
EINECS: 221-696-4
SAFETY DATA SHEET (SDS)
Update Date: 2023-05-04 17:34:37

What is DIETHYL DIALLYLMALONATE?

The Uses of DIETHYL DIALLYLMALONATE

Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke?s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Definition

ChEBI: Diethyl diallylmalonate is a fatty acid ester.

General Description

Low catalyst loading in ring-closing metathesis reaction of diethyl diallylmalonate has been reported. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Properties of DIETHYL DIALLYLMALONATE

Boiling point:	128-130 °C/12 mmHg (lit.)
Density	0.994 g/mL at 25 °C (lit.)
vapor pressure	4.266Pa at 25℃
refractive index	n20/D 1.446(lit.)
Flash point:	>230 °F
storage temp.	Sealed in dry,Room Temperature
solubility	Chloroform, DMSO, Methanol
form	Oil
color	Clear Colourless
Water Solubility	Sparingly Soluble in water. (0.72 g/L) (25°C)
BRN	1790529
CAS DataBase Reference	3195-24-2(CAS DataBase Reference)

Safety information for DIETHYL DIALLYLMALONATE

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.