DIETHYL (CHLOROMETHYL)PHOSPHONATE
Synonym(s):Chloromethylphosphonic acid diethyl ester;NSC 67753
- CAS NO.:3167-63-3
- Empirical Formula: C5H12ClO3P
- Molecular Weight: 186.57
- MDL number: MFCD00010189
- EINECS: 221-632-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is DIETHYL (CHLOROMETHYL)PHOSPHONATE?
Chemical properties
Clear colorless to light yellow liquid
The Uses of DIETHYL (CHLOROMETHYL)PHOSPHONATE
Reactant involved in:
- Subsequent alkylation after nucleophilic substitution
- One-pot alkylation-boration of α-haloalkylphosphonates
- Synthesis of cyclpentane and pyrrolidine derivatives via regioselective insertion reactions
- Phosphorylation leading to P-containing cyclopropanes
- Wadsworth-Emmons reactions
- Ring expansion of zircnacycles via carbenoid insertion
Synthesis Reference(s)
Tetrahedron Letters, 28, p. 3799, 1987 DOI: 10.1016/S0040-4039(00)96387-1
Properties of DIETHYL (CHLOROMETHYL)PHOSPHONATE
Boiling point: | 109-110 °C10 mm Hg(lit.) |
Density | 1.2 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 188 °F |
storage temp. | 2-8°C |
form | Liquid |
color | Clear colorless to light yellow |
Specific Gravity | 1.2 |
BRN | 1363361 |
EPA Substance Registry System | Phosphonic acid, (chloromethyl)-, diethyl ester (3167-63-3) |
Safety information for DIETHYL (CHLOROMETHYL)PHOSPHONATE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for DIETHYL (CHLOROMETHYL)PHOSPHONATE
New Products
4-Fluorophenylacetic acid 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate (6-METHYL-[1,3]DITHIOLO[4,5-b]QUINOXALIN-2-ONE INDAZOLE-3-CARBOXYLIC ACID 4-IODO BENZOIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5,6-Dimethoxyindanone 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 2-aminopropyl benzoate hydrochloride 1-(4-(aminomethyl)benzyl)urea hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
DIMETHYLPHENYLPHOSPHINE
Dimethyl(piperidin-2-yl)phosphine oxide hydrochloride
Dimethyl(pyrrolidin-2-yl)phosphine oxide hydrochloride
DIETHYL (CHLOROMETHYL)PHOSPHONATE
TRIETHYL 2,2-DICHLORO-2-PHOSPHONOACETATE
Triethyl 2-chloro-2-phosphonoacetate
DIBUTYL CHLOROMETHYL PHOSPHONATE
AURORA KA-1461
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